Demulsification is the breaking of a crude oil emulsion into oil and water phases. A fast rate of separation, a low value of residual water in the crude oil, and a low value of oil in the disposal water are obviously desirable. Produced oil generally has to meet company and pipeline specifications. For example, the oil shipped from wet-crude handling facilities must not contain more than 0.2% basic sediment and water (BS&W) and 10 pounds of salt per thousand barrels of crude oil. This standard depends on company and pipeline specifications. The salt is insoluble in oil and associated with residual water in the treated crude. Low BS&W and salt content is required to reduce corrosion and deposition of salts. The primary concern in refineries is to remove inorganic salts from the crude oil before they cause corrosion or other detrimental effects in refinery equipment. The salts are removed by washing or desalting the crude oil with relatively fresh water. This stability arises from the formation of interfacial films that encapsulate the water droplets. To separate this emulsion into oil and water, the interfacial film must be destroyed and the droplets made to coalesce.
The electromagnetic heating of oil wells and reservoirs refers to thermal processes for the improved production of oil from underground reservoirs. The source of the heat, generated either in the wells or in the volume of the reservoir, is the electrical energy supplied from the surface. This energy is then transmitted to the reservoir either by cables or through metal structures that reach the reservoir. The main effect, because of the electrical heating systems used in practice in enhanced oil recovery, has been the reduction of the viscosity of heavy and extra heavy crudes and bitumens, with the corresponding increase in production. Focus is centered on systems (and the models that describe their effects) that have been used for the electromagnetic heating in the production of extra heavy petroleum and bitumen.
Cold heavy oil production with sand (CHOPS) involves the deliberate initiation of sand influx during the completion procedure, maintenance of sand influx during the productive life of the well, and implementation of methods to separate the sand from the oil for disposal. No sand exclusion devices (screens, liners, gravel packs, etc.) are used. The sand is produced along with oil, water, and gas and separated from the oil before upgrading to a synthetic crude. To date, deliberate massive sand influx has been used only in unconsolidated sandstone (UCSS) reservoirs (φ 30%) containing viscous oil (μ 500 cp). It has been used almost exclusively in the Canadian heavy-oil belt and in shallow ( 800 m), low-production-rate wells (up to 100 to 125 m3/d).
Although conformance-improvement gel treatments have existed for a number of decades, their widespread use has only begun to emerge. Early oilfield gels tended to be stable and function well during testing and evaluation in the laboratory, but failed to be stable and to function downhole as intended because they lacked robust chemistries. Also, because of a lack of modern technology, many reservoir and flooding conformance problems were not understood, correctly depicted, or properly diagnosed. In addition, numerous individuals and organizations tended to make excessive claims about what early oilfield gel technologies could and would do. The success rate of these gel treatments was low and conducting such treatments was considered high risk. As a result, conformance-improvement gel technologies developed a somewhat bad reputation in the industry. Only recently has this reputation begun to improve. The information presented in this chapter can help petroleum engineers evaluate oilfield conformance gels and their field application on the basis of well-founded-scientific, sound-engineering, and field-performance merits.
Actually, the definition of a tight gas reservoir is a function of many factors, each relating to Darcy's law. The main problem with tight gas reservoirs is that they do not produce at economic flow rates unless they are stimulated--normally by a large hydraulic fracture treatment. Eq. 7.1 illustrates the main factors controlling flow rate.
The claim that the world is irresponsible in rapidly consuming irreplaceable resources ignores technical progress, market pressures, and the historical record. For example, the "Club of Rome," with the use of exponential growth assumptions and extrapolations under static technology, predicted serious commodity shortages before 2000, including massive oil shortages and famine. First, the new production technologies are proof that science and knowledge continue to advance and that further advances are anticipated. Second, oil prices will not skyrocket because technologies such as manufacturing synthetic oil from coal are waiting in the wings. Third, the new technologies have been forced to become efficient and profitable, even with unfavorable refining penalties. Fourth, exploration costs for new conventional oil production capacity will continue to rise in all mature basins, whereas technologies such as CHOPS can lower production costs in such basins. Fifth, technological feedback from heavy-oil production is improving conventional oil recovery. Finally, the heavy-oil resource in UCSS is vast. Although it is obvious that the amount of conventional (light) oil is limited, the impact of this limitation, while relevant in the short term (2000 to 2030), is likely to be inconsequential to the energy industry in the long term (50 to 200 years). The first discoveries in the Canadian heavy-oil belt were made in the Lloydminster area in the late 1920s. Typically, 10- to 12-mm diameter perforations were used, and pump jacks were limited by slow rod-fall velocity in the viscous oil to a maximum of 8 to 10 m3/d of production, usually less. Operators had to cope with small amounts of sand, approximately 1% in more viscous oils. Small local operators learned empirically that wells that continued to produce sand tended to be better producers, and efforts to exclude sand with screens usually led to total loss of production. Operators spread the waste sand on local gravel roads and, in some areas, the roadbeds are now up to 1.5 m higher because of repeated sand spreading. The sharp oil price increases in the 1970s and 1980s led to great interest in heavy-oil-belt resources (approximately 10 109m3). Many international companies arrived and introduced the latest screen and gravel-pack technology but, in all cases, greatly impaired productivity or total failure to bring the well on production was the result. To this day, there are hundreds of inactive wells with expensive screens and gravel packs. The advent of progressing cavity (PC) pumps in the 1980s changed the nonthermal heavy-oil industry in Canada. The first PC pumps had low lifespans and were not particularly cost-effective, but better quality control and continued advances led to longer life and fewer problems. The rate limits of beam pumps were no longer a barrier and, between 1990 and 1995, operators changed their view of well management.
Case studies can be instructive in the evaluation of other coalbed methane (CBM) development opportunities. The San Juan basin, located in New Mexico and Colorado in the southwestern U.S. (Figure 1), is the most prolific CBM basin in the world. It produces more than 2.5 Bscf/D from coals of the Cretaceous Fruitland formation, which is estimated to contain 43 to 49 Tscf of CBM in place. For a long time, the Fruitland formation coals were recognized only as a source of gas for adjacent sandstones. In the 1970s, after years of encountering gas kicks in these coals, operators recognized that the coal seams themselves were capable of commercial gas rates. CBM development benefited greatly from drilling and log data compiled from previous wells targeting the deeper sandstones and an extensive pipeline infrastructure that was built to transport conventional gas. These components, along with a U.S. federal tax credit and the development of new technologies such as openhole-cavity completions, fueled a drilling boom that resulted in more than 3,000 producing CBM wells by the end of 1992. The thickest Fruitland coals occur in a northwest/southeast trending belt located in the northeastern third of the basin. Total coal thickness in this belt locally exceeds 100 ft and individual coal seams can be more than 30 ft thick. The coals originated in peat swamps located landward (southwest) of northwest/southeast trending shoreline sandstones of the underlying Pictured Cliffs formation. The location of the thickest coals (Figure 1) coincides with the occurrence of overpressuring, high gas content, high coal rank, and high permeabilities in the San Juan fairway ("fairway"). The overpressuring is artesian in origin and is caused by water recharge of the coals through outcrops along the northern margin of the basin. This generates high vertical pressure gradients, ranging from 0.44 to 0.63 psi/ft, which allow a large amount of gas to be sorbed to the coal. Coal gas in the San Juan basin can contain up to 9.4% CO2 and 13.5% C2 . Chemical analyses suggest that thermogenic gases have been augmented by migrated thermogenic and secondary biogenic gas sources, resulting in gas contents ranging up to 700 ft 3 /ton. Coal rank in the fairway ranges from medium- to low-volatile bituminous and roughly coincides with those portions of the basin that were most deeply buried. Coals in the fairway typically have low ash and high vitrinite contents, resulting in large gas storage capacities and excellent permeabilities of 10 md from well-developed cleat systems.
This page provides a brief review of illustrative field applications of polymer waterflooding as reported in the literature. In 1983, Manning et al. published a comprehensive and classic summary of the field results and performance of more than 250 polymer waterflooding projects and provided information relating to the early field applications of polymer waterflooding. Figure 1 shows the incremental oil production response for the North Burbank polymer flood. A polymer waterflooding project that involved a large full-field flooding project at the North Oregon Basin field in Wyoming's mature Big Horn Basin oil-producing area was reported in 1986 to be producing 2,550 BOPD of incremental oil production. It was reported that this polymer flooding project would recover ultimately more than 10 million bbl of incremental reserves from the mature North Oregon Basin field. The field project involved the flooding of both a fractured carbonate formation and a fractured sandstone formation with a polymer flood using partially hydrolyzed polyacrylamide(HPAM).
Core analyses are a critical part of analyzing CBM reservoirs to determine gas saturations. Coal cores must be placed in desorption canisters and heated to reservoir temperature. As the coal desorbs, gases are captured, and both their volume and composition are determined. Desorption continues for up to several months until the rate at which gas is being liberated from the coal becomes very small. At this point, the canisters are opened, and the cores can be described. The cores then are crushed in a mill that captures any remaining gas (residual gas), and the milled coal is mixed thoroughly to form a representative sample. An alternative to crushing the entire core is to first slab the core and crush one-half.
Liang, Xing (PetroChina Zhejiang Oilfield) | Wang, Gao-Cheng (PetroChina Zhejiang Oilfield) | Pan, Feng (Schlumberger) | Rui, Yun (PetroChina Zhejiang Oilfield) | Wang, Yue (Schlumberger) | Zhang, Lei (PetroChina Zhejiang Oilfield) | Mei, Jue (PetroChina Zhejiang Oilfield) | Li, Kai-Xuan (Schlumberger) | Zhao, Hai-Peng (Schlumberger)
Understanding mineral composition and depositional mechanisms aids in evaluating gas in place and mechanical properties of shale reservoirs. A method developed to delineate mineral variations and depositional setting combines borehole elemental concentration logs with borehole electrical image logs. Borehole elemental concentration logs provide a continuous measurement of the concentrations of more than 20 elements, which data help in obtaining quantities of mineralogical constituents. Electrical borehole images are used to identify in situ depositional features. Regional mapping of variations of mineral constituents and depositional features indicates sedimentary facies distribution.
The Lower and Upper WuFeng-LongMaxi Formation was studied in 27 wells spanning 100 km west-east across the southern SiChuan basin. From elemental spectroscopy, argillaceous, carbonate, and siliceous lithologies were identified; these were examined by scanning electron microscope (SEM) to investigate their mineralogy and geological origin. Argillaceous minerals were primarily supplied by terrigenous sediments, the majority of carbonate minerals originated from chemical precipitation, and siliceous minerals are associated with siliceous-shell organisms in the Lower WuFeng-LongMaxi strata and terrigenous influx in the Upper LongMaxi strata. A transgressive lag occurring at the base of the WuFeng formation corresponds to carbonate pebbles in cores and bedding-parallel gravels on borehole images. Silty layers deposited by turbidity currents that mainly appear in Upper LongMaxi Formation were readily identified on borehole images.