Although reserves estimates for known accumulations historically have used deterministic calculation procedures, the 1997 SPE/WPC definitions allow either deterministic or probabilistic procedures. Each of these is discussed briefly in the next two sections. Thereafter--except for another section on probabilistic procedures near the end--the chapter will focus on deterministic procedures because they still are more widely used. Both procedures need the same basic data and equations. Deterministic calculations of oil and/or gas initially in place (O/GIP) and reserves are based on best estimates of the true values of pertinent parameters, although it is recognized that there may be considerable uncertainty in such values.
Chemical treatment with demulsifiers is used to counteract the natural surfactants present, and wetting agents or other chemicals sometimes are used to carry the suspended solids into the water layer. The presence of a band of emulsion in centrifuged samples indicates that further chemical treatment might be needed.