Novel Switchable Alkyl-Amine Surfactants for CO2 Emulsion

Cui, Leyu (TOTAL S.A) | Klimenko, Alexandra (TOTAL S.A) | Dubos, Fabienne (TOTAL S.A) | Lagorse, Marine (TOTAL S.A) | Bourrel, Maurice (TOTAL S.A)



CO2 emulsion/foam is a promising method for controlling the mobility and improving the volumetric sweep efficiency in CO2 enhanced oil recovery (CO2-EOR) process. Recently, amine surfactants attract the attention of the researchers as CO2 emulsifiers/foamers, because of their switchable property: the surfactants are nonionic and CO2 soluble at high pH, and are cationic and water soluble at low pH. However, the efficiency of the commercial switchable amine surfactants is usually suppressed at high salinity (> 200 g/L TDS) and temperature (> 100 °C). Thus, novel switchable alkyl-amine surfactants are designed in house based on the hydrophilic and CO2-philic balance for rapidly generating strong and stable CO2 emulsions at high salinity and high temperature. These novel surfactants are evaluated and compared to a commercial one with respect to the solubility in brine and CO2, and emulsifying ability in bulk and in porous media at high temperature, high pressure and high salinity.

The novel surfactants show outstanding performance: soluble in 220 g/L NaCl brine at pH≤8 from room temperature to 120 °C, soluble in CO2 at relatively low pressure (91 bar) and high temperature (110 °C). The surfactants are thermally stable at 110 °C and pH=4 in the absence of O2. Strong CO2 emulsion/foam is observed in both bulk test and in silica sandpack with 0.2 (wt)% of the surfactant in brine. Additionally, the apparent viscosity of the CO2 emulsion/foam at 110 °C is significantly higher than that at lower temperatures. Comparing to the commercial surfactants, the CO2 emulsion/foam is stronger and generated faster by the novel surfactants. These novel surfactants can be synthesized using commercially available feeds and simple industrial processes. Thus, the novel surfactants are promising for generating the CO2 emulsion/foam, especially in the hot and salty carbonate reservoirs.