Controls on CH4 Adsorption on Shales: Characterisation of Beetaloo Sub-Basin Gas Shales and Comparison to Global Shales

Sander, Regina (CSIRO Energy) | Pan, Zhejun (CSIRO Energy) | Connell, Luke D (CSIRO Energy) | Camilleri, Michael (CSIRO Energy) | Grigore, Mihaela (CSIRO Energy)



The Beetaloo Sub-basin in the Northern Territory is one of Australia's most prospective basins for shale gas production. The Beetaloo gas shales are unique in that they could become some of the oldest producing source rocks in the world, if commercialized successfully. In this work we characterise gas shales from two target reservoirs in the Beetaloo Sub-basin and compare them to other shales from around the globe to improve the current understanding of what controls gas adsorption on shales.

We characterise the methane adsorption capacity of two sets of Beetaloo shale samples: middle Velkerri B shale (8 samples, ~2450 m depth) and lower Kyalla shale (10 samples, ~1300 m depth). Measurements are performed at reservoir conditions, i.e. up to 110°C and 30 MPa, using CSIRO's gravimetric isotherm rig. The samples’ mineralogy is analysed using X-ray powder diffraction (XRD) and the total organic carbon (TOC) is determined using a LECO machine.

Our experiments demonstrate that the gravimetric rig is capable of obtaining fast and reliable measurements on low adsorbing shales at high pressures and high temperatures for sample quantities of around 90 g. The results highlight that the adsorption capacity of middle Velkerri B shale is significantly higher than of lower Kyalla shale (average Langmuir volume 3.23 m3/t compared to 2.27 m3/t) and that the isotherms can be represented using a Langmuir relationship. In spite of their age, the Beetaloo shales exhibit adsorption behaviour comparable to that of other shales with similar TOC.

Two global shale data sets, which include the Beetaloo samples, demonstrate that there is a strong relationship between TOC and a shale's adsorption capacity. However, the TOC alone cannot account for the differences in adsorbed amount observed within the two sets of Beetaloo shale samples.

Bulk clay content appears to control the adsorption capacity of shales with low TOC (< 2%), such as the lower Kyalla shale. Analysis assessing the contribution of individual clay minerals to the CH4 adsorption capacity indicates that it is the high illite/muscovite content (30-40%) that controls adsorption on the lower Kyalla shale samples. For the high TOC/low clay middle Velkerri B samples (3.7-6.3% TOC, 20-23% clay) clay content cannot account for the differences observed in adsorbed gas between the samples, even as a secondary control. Further investigation is required to understand what controls gas adsorption on this shale.

  Geologic Time: Phanerozoic > Paleozoic (1.00)
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  Technology: Information Technology (0.46)