PEH:Well-To-Well Tracer Tests - PetroWiki

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A passive tracer that labels gas or water in a well-to-well tracer test must fulfill the following criteria. It must have a very low detection limit, must be stable under reservoir conditions, must follow the phase that is being tagged and have a minimal partitioning into other phases, must have no adsorption to rock material, and must have minimal environmental consequences. The tracers discussed in the following sections have properties that make them suitable for application in well-to-well test in which dilution volumes are large. For small fields in which the requirement with respect to dilution is less important, other tracers can be applied. Figure 1.1 – Production curve of S14CN compared with the production curve of HTO in a dynamic flooding laboratory test (carbonate rock) (after Bjørnstad and Maggio[2]). There are no possibilities for thermal degradation, and it follows the water closely. The 36Cl- is a long-lived nuclide (3 105 years), and the detection method is atomic mass spectroscopy rather than radiation measurements. The disadvantage is that the analysis demands very sophisticated equipment and is relatively time consuming. For mono-valent anions, the retention factors (see Eq. 6.2) are in the range of 0 to -0.03, which means that such tracers pass faster through the reservoir rock than the water itself (represented by HTO). A compound such as 35SO42- may be applied in some very specific cases but should be avoided normally because of absorption. Some anionic tracers may show complex behavior. Radioactive iodine (125I- and 131I-) breaks through before water but has a substantially longer tail than HTO. Both a reversible sorption and ion exclusion seem to play a role here. Cationic tracers are, in general, not applicable; however, experiments have qualified 22Na as an applicable water tracer in highly saline (total dissolved solids concentration seawater salinity) waters. In such waters, the nonradioactive sodium will operate as a molecular carrier for the tracer molecule. Retention factor has been measured in the range of 0.07 (see Eq. 6.2) at reservoir conditions in carbonate rock (chalk). Wood[6] reported the use of 134Cs, 137Cs, 57Co, and 60Co cations as tracers.

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