Late cycles of cyclic steam stimulation (CSS) are characterized by a decreasing heavy-oil recovery and an increasing water cut. Nickel nanoparticles can be used to promote aquathermolysis reactions between water and heavy oil in steam-injection processes, thereby increasing the recovery factor (RF). In this paper, detailed investigations were performed to determine the optimal operational parameters and answers to the following questions:
CSS experiments were conducted between temperatures of 150 and 220°C. Steam generated under these temperatures was injected into sandpacks saturated with Mexican heavy oil. Powder-form nickel nanoparticle was introduced into this process to boost the oil production. In an attempt to obtain the optimal concentration, different concentrations were tested. Next, oil sands without any nanoparticle additives were first added into the cylinder. Then, only one-third of the sandpack was mixed with nickel nanoparticles near the injection port. Experiments were executed to study the effects of temperature, nickel concentrations, and nanoparticle-penetration depth on the ultimate oil recovery and produced oil/water ratios after each cycle. Produced-oil quality and emulsion formation were evaluated with gas-chromatography (GC) analysis, viscosity measurements, saturates/asphaltenes/resins/aromatics (SARA) tests, and microscopic analysis of the effluents.
Experimental results show that the best concentration of nickel nanoparticles, which gives the highest ultimate oil RF, is 0.20 wt% of initial oil in place (IOIP) under 220°C, whereas the nickel concentration of 0.05 wt% provides the highest RFs at the early stages. A lower temperature of 150°C provides a much-lower RF than 220°C, which is mainly because of a lower level of aquathermolysis reactions at 150°C. By analyzing the compositions of produced oil and gas samples with GC and SARA tests, we confirm that the major reaction mechanism during the aquathermolysis reaction is the breakage of the carbon/sulfur (C/S) bond; the nickel nanoparticles can act as catalyst for the aquathermolysis reaction; and the catalytic effect becomes less remarkable from cycle to cycle. One run of the experiment to test the effect of particle-penetration depth revealed that the nickel nanoparticles distributed near the injection port greatly contributed to the ultimate RF.
Our recent experimental studies on superheated solvent injection for heavy-oil recovery showed that when a solvent is injected into the reservoir, the process is highly sensitive to pressure and temperature. The effects of these parameters on the recovery factor (RF) are accentuated when the operating conditions are closer to the saturation curve of the solvent injected. This paper investigates this process and formulates the optimal field-scale application conditions that yield the maximum profit, as a continuation of previous work. To achieve this, a hypothetical field-scale numerical model was constructed, and the key parameters identified through the aforementioned sensitivity analysis were incorporated. Then, the injection process was simulated for a two-horizontal injection/production pattern. An optimization study was performed to identify the relative contributions of the effective parameters (pressure, temperature, and injection rate) and to propose an optimal application scheme with a genetic algorithm (GA). The critical pressure and temperature yielding maximum production and highest profit considering solvent retrieval were defined for different injection rates and application scenarios. Our results indicate that, at the end of the hot solvent-injection process, an important volume of solvent is left in the reservoir, and its volume depends on the injection–production scheme selected. Nevertheless, if the project is performed under appropriately selected operational parameters (obtained through the optimization processes) and followed by the proper process to retrieve the solvent from the reservoir (low-temperature steam or hot-water applications), it can make the hot solvent-injection process profitable.
Capillary imbibition tests are commonly applied to measure wettability-alteration potential of chemicals. However, these tests are exhaustive, time-consuming, and expensive, and the underlying physics of the alteration process from a surface-chemistry point of view is often limited and/or unexplained. Contact-angle measurement is a quicker and more-feasible screening tool to assess the emerging wettability modifiers. It also provides visual data on the mechanics of the wettability-alteration process. This paper focuses on contact-angle measurements as a means to evaluate the wettability alteration on mineral plates and porous-rock samples. Imidazolium ionic liquids were tested at different concentrations. To study the effect of pH on the wettability, sodium chloride and sodium borate were used at different concentrations. The composition of divalent ions was varied because of their possible use with low-high-salinity water as wettability-alteration agents. Unmodified and surface-modified silica, zirconium, and alumina nanoparticles were also tested.
Contact-angle measurements were performed initially on mica, marble, and calcite plates. Experiments were repeated on polished surfaces of Berea sandstone, Indiana limestone, and cleaned Grosmont carbonate cores. Oils (pure and solvent-mixed crude oils) with different viscosities and densities were used to test the effect of oil type on the process. The images were obtained by an single-lens reflex (SLR) camera at different temperatures ranging from 25 to 80°C. By testing with different concentrations, the optimum chemicals were found for different mineral-plate/porous-rock systems. Then, the results were cross checked with the imbibition tests performed on the same samples to validate the contact-angle-measurement observations.
Thermal-stability tests were also performed in case of their use during or after a thermal method. For the thermal-stability tests, contact-angle experiments were conducted in a high-pressure andhigh-temperature (up to 200°C) cell. It was shown that certain ionic liquids and nanofluids are stable at high temperatures and can be efficiently used at low concentrations.
Reservoirs containing very heavy oil or extremely heterogeneous/fractured geology are not convenient for steamflooding and even cyclic steam injection. Then, steam can be used to heat the reservoir and accelerate the recovery by gravity drainage. Two well-known applications of this method are steam assisted gravity drainage (SAGD) and thermally assisted gas oil gravity drainage. Although the latter is not commercially applied, the former is a proven technology with remarkable production in Canada and Venezuela. Due to the risks caused by the cost and solvent retention, no large scale applications of solvent injection with steam have been implemented. An alternative is to use chemicals as suggested a few decades ago to alter the interfacial forces and improve microscopic displacement. This paper presents experimental results on testing -new generation- chemicals for their capability in recovery improvement.
Sandpack experiments were conducted to evaluate the incremental in oil recovery by chemical additives compared to sole steam injection. Steam and chemicals were heated and introduced to the system from separate channels at the entrance of the vertically situated sandpack (30 cm long, 5 cm in diameter). To generate a purely gravity dominated system (pressure differential of 10–25 psi) a back pressure regulator was used. The chemicals used include thermally stable surface agents, such as surfactants (AAS J1111, O352, LTS-18), Tween 20, biodiesel), ionic liquid (BMMIM BF4), high pH solution (NaBO2), solvent (heptane), and nanoparticles (SiO2). The oil selected was 20,000 cp crude.
Incremental recoveries were monitored and related to the thermal stability of the chemicals. A comparative analysis was provided as to their contribution to the reduction of the cost (less steam and lower temperature) and chemicals were classified based on their recovery improvement performance and thermal stability. Through this experimental schematic, the highest increment in oil recovery was achieved by LTS-18 but also combined a high duration of the experiment with a high water consumption. This reduces the result in economical favorable conditions of the LTS-18. Biodiesel had the best performances in steam-to-oil ratio (SOR) and its effects needs to be further investigated. Tertiary injection of hot water with a surfactant was inefficient. Ionic liquid increased the oil recovery in the tertiary stage after the core was flooded with a low quality steam by 20%.
Over a 6-month time frame in 2016, I was able to attend three SPE conferences on heavy oil in different countries spanning three continents (Canada, Peru, and Kuwait). Despite regional differences in the applications, potentials, problems, and technological needs, the common theme in all conferences was “low cost.” Cost optimization in heavy-oil production was discussed from technical and economic perspectives, not only in the technical sessions but also in numerous panel discussions.
Such optimization can be achieved through numerical modeling to suggest general optimal strategies and development plans or by using proper real-time data acquisition (production optimization) for prompt decisions while operations are ongoing. This requires continuous monitoring of the processes as seen in many steam-assisted-gravity-drainage operations or other types of steam-injection applications. I selected two papers about advanced monitoring techniques as suggested reading in this issue.
Moreover, chemical and nanomaterial additives to water and steam have received a great deal of attention. Low-interfacial-tension (microemulsion) and low-salinity injection in heavy oils in sands and carbonates and wettability alteration in carbonates were common topics at conferences held over the past year. I selected one review paper for additional reading and one experimental work as a summary paper on this subject. Apparently, modeling efforts on advanced (but unconventional) technologies such as electromagnetic heating have continued. You will find a detailed mathematical analysis of the process in one of the papers summarized.
Despite the recent economic downturn, we were able to hear the outcome of current field practices at pilot or demonstration scale. Papers detailing small-scale cyclic-steam-injection applications in Kuwait and Oman were worth reading, and one article on this specific subject is included here. Considering these activities in the Middle East, effective transfer of technologies from North America to that part of the world will become highly critical in the near future.
Recommended additional reading at OnePetro: www.onepetro.org.
SPE 181160 State-of-the-Art Review of the Steam Foam Process by Eric Delamaide, IFP Technologies Canada, et al.
SPE 180732 An Integrated Probabilistic Work Flow for Primary and Thermal Performance Prediction of a Large Extraheavy-Oil Field by Raushan Kumar, Chevron, et al.
SPE 181431 Horizontal Steam-Injection Flow Profiling Using Fiber Optics by Mahdy Shirdel, Chevron Energy Technology Company, et al.SPE 180726 SAGD Production Observations Using Fiber-Optic Distributed Acoustic and Temperature Sensing: SAGD DAS—Listening to Wells To Improve Understanding of Inflow by Warren MacPhail, Devon, et al.
One of the ways to improve the efficiency of steam injection is to use chemicals as an additive to alter interfacial properties. Historically, this has been tested using surfactants, which are expensive and thermally unstable. Therefore, commercial applications have been highly limited in that area over the past three decades. In conjunction with recent efforts using new generation materials as EOR agents, we performed a screening study to identify the potential chemicals/materials for heavy-oil recovery and to investigate the applicability of selected new generation chemicals as interfacial properties modifiers at steam temperature.
Different experimental methods, including capillary imbibition tests, i.e. contact angle and interfacial tension measurements, were combined to understand the mechanism of alteration surface interplay (wettability and interfacial tension) using different chemical agents. Capillary imbibition tests were conducted to study the potential of these chemicals to alter wettability and rock/chemical interactions on limestone and aged sandstone cores at high temperature. Pendant drop interfacial tension (IFT) and contact angle measurements were performed using a high pressure and high temperature cell under the same -steam- conditions.
Seven different chemical agents including a high pH solution (sodium metaborate), an ionic liquid, a cationic and an anionic surfactant, and nanofluids (aluminum and zirconium oxides) were tested in this study. Indiana limestone samples were saturated and aged in heavy oil with a viscosity of 6,000 cp. Capillary imbibition tests were conducted under high temperature (between 90°C and 180°C) and high pressure (185 psi) conditions using a newly-manufactured visual cell. The production rate and ultimate recovery were used to evaluate the capability of different chemicals changing the interfacial properties and their thermal stability at steam temperature. Contact angles between heavy oil and calcite plates were measured under the same conditions. Finally, the stability of the chemicals was measured through settlement tests at steam temperature conditions as well as TGA (thermal gravimetric analysis). The combination of all these results helped identify the applicability of the selected chemicals under steam conditions for carbonates. Technical and economic limitations for each chemical as well as the way the chemical contributes to recovery (wettability alteration or IFT reduction) were identified.
Investigation of interfacial properties alteration induced by new generation chemicals at high temperature is helpful in the selection and application of efficient and economical chemicals in steam based heavy-oil recovery methods.
Light-hydrocarbon solvent injection is an effective process to improve heavy-oil/bitumen recovery from oil sands. In this process, oil production is achieved by gravity drive, which is enhanced through the dilution of oil by injected solvent. However, solvent retrieval is one of the major economic concerns in defining the viability of this technique. In this research, a sandpack experimental study was conducted, and the solvent retrieval was determined on the basis of thermodynamic conditions and fluid characterization. Two heavy-oil samples (8.6 °API and 10.28 °API) from different fields in Alberta, Canada, and four light-hydrocarbon solvents (propane, n-hexane, n-decane, and distillate hydrocarbon) were used in this experimental scheme. Results showed that solvent retrieval increases when light-hydrocarbon solvents (propane and distillate hydrocarbon) are used compared with solvent with high molecular weight (n-hexane and n-decane). Temperature and pressure highly influenced the solvent retrieval. The percentage of solvent retrieval increased when the hydrocarbon solvent was closer to the vapor phase (dewpoint). However, oil recovery showed significant reduction when propane and n-hexane were injected because of high asphaltene deposition on the sandpack. The maximum solvent retrieval was calculated to be nearly 98% at 120°C and 698.47 kPa when propane-and-distillate hydrocarbon was used as solvent. Formation damage, on the other hand, may increase when propane is used as solvent because of the high asphaltene deposition.
This paper presents an extensive analysis solvent injection at elevated temperatures to recover heavy- oil/bitumen from fractured carbonates. Three different solvents (propane, heptane and distillate oil - naphtha) were injected at different temperatures representing a wide range of carbon number. Indiana limestone (outcrop) and vuggy naturally fractured carbonate samples (outcrop core samples from a producing formation in Mexico) were selected as core samples. Hot solvent was injected continuously through artificially fractured cores followed by hot water (or steam injection) phase. The optimal temperatures for heavy oil recovery and solvent retrieval, in the subsequent hot water injection, for each kind of rock sample and type of solvent were determined. The results revealed that heavy oil recovery increase with the solvent carbon number used. Also, it was observed that when the temperature is higher than the saturation value for the given pressure curve, the recovery decreases and the lightest component of the heavy oil are dragged by the gas stream.
Late cycles of cyclic steam stimulation (CSS) are characterized with a decreasing heavy-oil recovery and an increasing water cut. Nickel nanoparticles can be used to promote aquathermolysis reactions between water and heavy oil in steam injection processes, thereby increasing the recovery factor. In this paper, detailed investigations were performed to determine the optimum operational parameters and answers to the following questions: (1) What is the optimum concentration of nickel nanoparticles for promoting aquathermolysis under high steam temperature?; (2) Can we improve oil recovery at lower steam temperatures with the presence of nickel nanoparticles?; (3) What effect does the penetration depth of nickel nanoparticles have on the final oil recovery?
CSS experiments were conducted between temperatures 150°C and 220°C. Steam generated under these temperatures was injected into sand packs saturated with Mexican heavy oil. Powder-form nickel nanoparticle was introduced into this process to boost the oil production. In an attempt to obtain the optimum concentration, different concentrations were tested. Next, oil sands without any nanoparticle additives were first added into the cylinder. Then, only one third of the sand pack was mixed with nickel nanoparticle near the injection port. Experiments were executed to study the effects of temperature, nickel concentrations, and nanoparticle penetration depth on the ultimate oil recovery and produced oil-water ratios after each cycle. Produced oil quality and emulsion formation were evaluated with gas-chromatography (GC) analysis, viscosity measurements, saturates-asphaltenes-resins-aromatics (SARA) test, and microscopic analysis of the effluents.
Experimental results show that the best concentration of nickel nanoparticles, which gives the highest ultimate oil recovery factor, is 0.20 wt% of initial oil in place (IOIP) under 220°C, while the nickel concentration of 0.05 wt% provides the highest recovery factors at the early stages. A lower temperature of 150°C provides a much lower recovery factor than 220°C, which is mainly due to a lower level of aquathermolysis reactions at 150°C. By analyzing the compositions of produced oil and gas samples with GC and SARA, we confirm that (1) the major reaction mechanism during the aquathermolysis reaction is the breakage of C-S bond, (2) the nickel nanoparticles can act as catalyst for the aquathermolysis reaction, and (3) the catalytic effect becomes less remarkable from cycle to cycle. One run of experiment to test the effect of particle penetration depth revealed that nickel nanoparticle distributed near the injection port greatly contributed to the ultimate recovery factor.
Heavy oil containing carbonate and sand reservoirs exhibits reverse wettability characteristics. Depending on temperature, the phase of injected steam, and rock type, the wettability may be altered to more water-wet. The addition of chemicals to hot-water (or steam) may further change the interfacial properties (more water-wet and less interfacial tension). Surfactants were tested extensively for this process in the past and their temperature resistance was an obstacle. New generation chemicals need further investigation from a technically and economically success point of view.
The objective was to investigate the alteration of interfacial properties induced by different types of chemical agents under hot conditions. To achieve this, three experimental tools (contact angle measurement, interfacial tension measurement, and spontaneous imbibition tests) were applied. High pressure and high temperature contact angle measurements enabled a quick method to identify the suitability of the chemicals for wettability modification. Interfacial tension between oil and different chemical solution was measured with a variation of temperature. In the imbibition tests, core samples were exposed to heating for longer time periods so that the temperature resistance of the chemicals was also tested. Imbibition experiments were conducted at ambient pressure and 90°C. The combination of the contact angle and interfacial tension provided insight into the recovery enhancement mechanisms.
Six different chemicals including an ionic liquid, three nano-fluids (silica, aluminum, and zirconium oxides), a cationic surfactant, and a high pH solution were chosen based on our screening study. Heavy-oil used was obtained from a field in Alberta (6,000cp). Contact angles were measured on mica, calcite, sandstones and limestones plates. The experimental temperature ranged from 25 to 200°C and pressure was changed to keep the solution in the aqueous phase. Promising modifiers for different rock types under different temperature were screened separately. Secondly, spontaneous imbibition tests were performed on sandstone and limestone cores with screened promising modifiers. Oil recovery in this phase was continuously monitored to evaluate wettability alteration capability and the mechanism(s) involved was analyzed for different chemicals.
Analysis of wettability alteration mechanisms and IFT reduction capabilities is expected to be useful in the selection of suitable and temperature-resistant chemicals for high temperature applications in different reservoir rocks.