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Collaborating Authors
Li, Chuncheng
Experimental Study of Surfactant-Assisted Oil Recovery in the Middle Bakken Cores
Zhang, Shaojie (Petroleum Engineering, University of North Dakota) | Li, Chuncheng (Petroleum Engineering, University of North Dakota) | Pu, Hui (Petroleum Engineering, University of North Dakota) | Ling, Kegang (Petroleum Engineering, University of North Dakota) | Sun, Runxuan (Petroleum Engineering, University of North Dakota) | Zhao, Julia Xiaojun (Department of Chemistry, University of North Dakota)
Abstract In this study, six core samples were obtained from the Middle Bakken Formation in North Dakota. Before the imbibition experiment, petrophysical analysis were conducted for the samples. XRD method was used to analyze the mineral composition. Nitrogen adsorption and SEM methods were combined to study the pore size distribution and microstructures. Then the authors performed brine imbibition and surfactant imbibition for six Bakken cores and two Berea sandstones. Before the experiment, the cores were fully filled with Bakken crude oil. The core plugs were then submerged into the brine and surfactant solutions with all-face-open (AFO) condition. Experiments of brine and surfactant imbibing into oil-filled cores were carried out with recording of recovered oil volume using imbibition cells. Different types of surfactants such as cationic, anionic, and nonionic, were tested in the study. Those experiments evaluate the oil displacement efficiencies of brine and different surfactants in Bakken rocks.
- North America > United States > North Dakota (1.00)
- North America > Canada > Saskatchewan (1.00)
- North America > Canada > Manitoba (1.00)
- Geology > Mineral > Silicate (0.51)
- Geology > Rock Type > Sedimentary Rock > Clastic Rock (0.36)
- North America > United States > South Dakota > Williston Basin > Bakken Shale Formation (0.99)
- North America > United States > North Dakota > Williston Basin > Bakken Shale Formation > Middle Bakken Shale Formation (0.99)
- North America > United States > Montana > Williston Basin > Elm Coulee Field > Bakken Shale Formation > Middle Bakken Shale Formation (0.99)
- (5 more...)
Abstract The utilization of synergistic mixtures of nanoparticles (NPs) and surfactants for enhanced oil recovery (EOR) has drawn increasing scientific attention. In this study, a series of coarse-grained (CG) molecular dynamics (MD) models were built to study the behaviors of NPs and surfactants in the vicinity of the oil/water interface. Hydrophilic, hydrophobic, and amphiphilic NPs were constructed to investigate the effect of hydrophobicity on the ability of NPs in term of interfacial tension (IFT) reduction. The synergistic effect of surfactants and NPs were also studied. Surfactants and amphiphilic NPs can both accumulate at the interface of oil and water, while hydrophilic and hydrophobic NPs stay in water or oil phase. The NPs with various ratios of hydrophobic to hydrophilic domains were investigated to determine the types of NPs that result in the most IFT reduction. The comparison of IFTs indicates that amphiphilic NPs has a better ability to assist surfactants in further reducing the interfacial tension. Meanwhile, surface modification and the presence of surfactants can prevent the aggregation of NPs. These MD simulation results allow us to figure out the physical behavior of NPs and surfactants at the oil/water interfaces. Analysis of the results can further assist the NPs synthesis for surfactant and/or surfactant-nanoparticle EOR applications in unconventional reservoirs. Introduction Enhanced Oil Recovery (EOR) is well known for its potential to produce residual oil after the primary and secondary oil recovery. The residual oil is trapped in the narrow throat due to high capillary pressure, which is influenced by rock wettability and oil/water interfacial tension (IFT) (Wu et al., 2008). Surfactants have been widely investigated and employed in the EOR process to reduce the IFT and to alter the wettability (Sheng et al. 2015; Kamal et al., 2017; Negin et al., 2017). However, during the surfactant flooding, surfactants can adsorb onto the rock surfaces. This may result in the reduction of their concentrations, which significantly reduce the efficiency of surfactants in practical applications. The high cost of surfactants also makes this potential loss a critical issue. Many researchers have focused their studies on reducing the adsorption of surfactants by adding various materials in the chemical formulations.