Currently, many reservoirs in the region approach the end of primary recovery phase where new techniques are needed to enhance recovery. Therefore, the need to optimize oil recovery from the current resources is very well understood by regional oil companies. To enhance oil recovery from current oil resources, field operators need to overcome the forces responsible for oil entrapment. Enhanced Oil Recovery techniques (EOR) introduce new energy into oil reservoirs to reduce the influence of these forces. Most of these resources contain light oil and are considered suitable candidates for either miscible or chemical EOR techniques. The first technique is challenged by the availability of suitable miscible gas. While, chemical EOR techniques are challenges by the high salt concentrations in the maturing oil reservoirs. The high salinity conditions encourage deficiencies in the performance of chemical EOR processes. Therefore, minimizing the effect of in situ salt on the injected chemical would impose tremendous improvement that leads to higher oil recovery. One way to diminish salt effect is to condition the oil reservoirs by injecting a slug of preflush water prior to chemical injection.
In this paper, the performance of polymer flooding, after preflush slug, in high salinity reservoir is investigated by numerical simulation means. The injected slugs, both preflush and polymer, are driven by water. The objective is to identify the relationship between preflush, polymer, and drive water characteristics and oil recovery. Seven parameters were considered: preflush slug size, preflush salinity, polymer slug size, polymer concentration, polymer slug salinity, and drive water salinity. The results show that these parameters have various degree of influence on oil recovery. For example, increasing the preflush slug size would results in more oil recovery especially during the early time. Detailed findings will be presented in the paper.
Telang, Milan (Kuwait Oil Company) | Al-Matrook, Mohammad F. (Kuwait Institute for Scientific Research) | Oskui, Gh. Reza (Kuwait Institute for Scientific Research) | Mali, Prasanna (Kuwait Oil Company) | Al-Jasmi, Ahmad (Kuwait Oil Company) | Rashed, Abeer M. (Kuwait Institute for Scientific Research) | Ghloum, Ebtisam Folad (Kuwait Institute for Scientific Research)
Asphaltene deposition problems in Kuwait have become a serious issue in a number of reservoirs during primary production in different fields, resulting in a severe detrimental effect on the economics of oil recovery. Hence, one of the mitigation approaches in the field is using remedial solvent treatments, such as Xylene or Toluene, which is very costly and harmful to the environment.
Kuwait Oil Company (KOC) is planning to produce from asphaltinic Marrat wells that have been shut down due to low bottom-hole pressure (BHP), by artificial lifting technique using an Electric Submersible Pump (ESP) supported with continuous chemical injection, as a pilot. The main objective of this study was to investigate in the lab the effectiveness of various concentrations of toluene/diesel (T/D) mixtures on Marrat reservoir fluid in order to mitigate asphaltene deposition problem during the actual pilot implementation.
Preliminary screening tests were conducted on the surface oil sample using Solid Detection System (SDS) "laser technique?? to determine the optimum dose of the T/D mixture ratio. The results showed that pure diesel accelerated the asphaltene precipitation; however, mixing T/D inhibited the precipitation process. Series of pressure depletion tests was then conducted on live oil , single phase samples, to determine the Asphaltene Onset Pressure (AOP) with and without adding various ration of T/D solvents at different temperatures from reservoir to surface conditions.
The results revealed that using 15% (by volume of oil) from the (50T:50D) mixture reduced the AOP close to the bubble point pressure. Furthermore, the amount of the precipitated asphaltene was physically quantified using a bulk filtration technique. It was observed that, based on blank sample, the wt% of the precipitated asphaltene was minimized at the AOP and maximized at the bubble point. However, using the recommended mixture of 50T/50D, the amount of asphaltene that precipitated was almost negligible. Therefore, from a health, safety, and economic point of view, this study recommends using a low dose of 7.5% (by volume of oil) from toluene mixture with diesel (50%:50%) rather than using pure toluene to prevent the precipitation.
Carbonate formations are very complex in their pore structure and exhibit a wide variety of pore classes. Pore classes such as interparticle porosity, moldic porosity, vuggy porosity, intercrystalline porosity, and microporosity. Understanding the role of pore class on the performance of emulsified acid treatment and characterizing the physics of the flow inside is the objective of our study.
The study was performed using vuggy dolomite cores that represent mainly the vuggy porosity dominated structure, while the homogenous cores represent the intercrystalline pore structure. Core flood runs were conducted on 6 x 1.5 in. cores using emulsified acid formulated at 1 vol% emulsifier and 0.7 acid volume fraction. The objective of this set of experiments is to determine the acid pore volume to breakthrough for each carbonate pore class at different injection rates.
In this paper, a novel approach to interpret the core flood run results using thin section observations, tracer experiments, SEM, and resistivity measurements will be presented. Thin section observations provide means to study the vugs size and their distribution, connectivity, and explain the contribution of the pore class in the acid propagation. Relating the rotating disk experiments of emulsified acid with dolomite to our core flood run results will be also conducted in order.
The acid pore volumes to breakthrough for vuggy porosity dominated rocks were observed to be much lower than that for homogenous carbonates (intercrystalline pore structure). Also, the wormhole dissolution pattern was found to be significantly different in vuggy rocks than that in homogenous ones. Comparison of thin section observations, tracer results and the core flood runs results indicates that the vugs are distributed in a manner that creates a preferential flow path which can cause a rapid acid breakthrough and effective wormholing than those with a uniform pore structure. Rotating disk experiment results, demonstrating that the reaction of emulsified acid with dolomite is much lower than that with calcite, showed that the reaction kinetics played a role in determining the wormhole pattern.
Historically, shale instability is a challenging issue when drilling reactive formations using water-based muds (WBM). Shale instability leads to shale sloughing, stuck pipe, and shale disintegration causing an increase in fines that affects the rate of penetration. To characterize shale instability, laboratory tests including Linear Swell Meter (LSM), shale-erosion and slake-durability are conducted in industry. These laboratory tests, under different flow conditions, provide shale-fluid interaction parameters which are indicative of shale instability. The composition of WBM is designed to optimize these interaction parameters, so that when used in the field the fluid helps achieve efficient drilling.
This paper demonstrates modeling of shale-fluid interaction parameters obtained from the LSM test. In the standard LSM test, a laterally confined cylindrical shale sample is exposed to WBM at a specific temperature and its axial swelling is measured with time. The swelling reaches a plateau which is characterized by a shale-fluid interaction parameter called % final swelling volume (A). A typical LSM test runs for around 48-72 hours and many tests may be needed to optimize fluid composition.
In this work, a method/model is developed to predict final swelling volume (A) as a function of the Cation exchange capacity (CEC) of the shale and salt concentration in the fluid (prominent factors affecting shale swelling). An empirical model in the form of A = f(CEC)*f(salt) which describes the explicit dependence on the influencing variables is developed and validated for 16 different shale samples at various salt concentrations. This model would significantly reduce LSM laboratory trials saving time and money. It could also enable rig personnel to obtain quick measure of shale characteristics so that WBM composition could be adjusted immediately to avoid shale instability issues.
In order to develop the design requirement with current regulatory and contemporary HSE practices, for a typical sour oil/gas production facility, a hypothetical case of about 3 mol % v/v H2S in gas and 300 ppm w/w H2S in oil, of multiphase feed stream, has been studied through the dispersion modeling for the conceptual stage. The findings indicated credible downwind lethal / semi lethal threat distance up to 300 meters. The conclusions of the H2S toxic risk assessment combined with the inherent safe design guidelines have yielded an entirely new set of requirement for the risk reduction. To start with it was realized that safe distance control room should be constructed and facilities should be designed for the remote operation, utilizing the new trends of foundation field bus, electronic marshaling and SIL-3 fiber optic sensors. The facility should be access controlled with mandatory PPE requirement of personal H2S monitors and personal quick donning (5 sec) escape SCABA (15 minutes capacity). The centrifugal compressors should be new generation design of enclosed and hermetically sealed type, levitated with magnetic bearing, without dry gas seals and oil lubrication. The vessels should be ASME Section VIII "lethal service?? design and plant piping should be as per fluid category "M?? of ASME B31.3 chapter VIII. Furthermore, stress relieving for thicknesses as low as 10 mm, rather than ASME B31.3 code specified >19 mm would be required. Small valves <4?? sizes should be of forged steel instead of cast steel. The export oil/gas pipelines and flow lines should be designed for =< 50~60 % of SMYS. Plate instead of Shell and Tube Exchangers. Adequate margins between vessels design and operating pressures to avoid PSV chattering. The PSV's to have acoustic monitoring. The facilities should be designed free of valve pits and internal corrosion monitoring pits.
In a past decade, various nanoparticle experiments have been initiated for improved/enhanced oil recovery (IOR/EOR) project by worldwide petroleum researchers and it has been recognized as a promising agent for IOR/EOR at laboratory scale. A hydrophilic silica nanoparticle with average primary particle size of 7 nm was chosen for this study. Nanofluid was synthesized using synthetic reservoir brine. In this paper, experimental study has been performed to evaluate oil recovery using nanofluid injection onto several water-wet Berea sandstone core plugs.
Three injection schemes associated with nanofluid were performed: 1) nanofluid flooding as secondary recovery process, 2) brine flooding as tertiary recovery processs (following after nanofluid flooding at residual oil saturation), and 3) nanofluid flooding as tertiary recovery process. Interfacial tension (IFT) has been measured using spinning drop method between synthetic oil and brine/nanofluid. It observed that IFT decreased when nanoparticles were introduced to brine.
Compare with brine flooding as secondary recovery, nanofluid flooding almost reach 8% higher oil recovery (% of original oil in place/OOIP) onto Berea cores. The nanofluid also reduced residual oil saturation in the range of 2-13% of pore volume (PV) at core scale. In injection scheme 2, additional oil recovery from brine flooding only reached less than 1% of OOIP. As tertiary recovery, nanofluid flooding reached additional oil recovery of almost 2% of OOIP. The IFT reduction may become a part of recovery mechanism in our studies. The essential results from our experiments showed that nanofluid flooding have more potential in improving oil recovery as secondary recovery compared to tertiary recovery.
The oil and gas industry must face the challenges to unlock the resources that are becoming increasingly difficult to reach with conventional technology. Most oil fields around the world have achieved the stage where the total production rate is nearing the decline phase. Hence, the current major challenge is how to delay the abandonment by extracting more oil economically. The latest worldwide industries innovation trends in miniaturization and nanotechnology material. A nanoparticle, as a part of nanotechnology, has size typically less than 100 nm. Its size is much smaller than rock pore throat in micron size. A nanoparticle fluid suspension, so called nanofluid, is synthesized from nano-sized particles and dispersed in liquids such as water, oil or ethylene glycol.
Through continuously increasing of publication addressed on the topic, nanofluid has showed its potential as IOR/EOR in the past decade. It has motivated us to perform research study to reveal the recovery mechanism and performance of nanofluid in porous medium. We focus on liphopobic and hydrophilic silica nanoparticles (LHP). Miranda et al. (2012) has mentioned the benefit of using silica nanoparticles. It is inorganic material that easier produced with a good degree of control/modify of physical chemistry properties. It can also be easily surface functionalized from hydrophobic to hydrophilic by silanization with hydroxyl group or sulfonic acid. Ju et al. (2006) has initially observed LHP with size range 10-500 nm could improve oil recovery with around 9% (with LHP concentration 0.02 vol. %) compared with pure water. They explained that the recovery mechanism involves wettability alteration of reservoir rock due to adsorbed LHP. Besides, they also reported the porosity and permeability impairment of sandpacks during nanofluid flooding.
Carbon dioxide (CO2) flooding is a conventional process in which the CO2 is injected into the oil reservoir to increase the quantity of extracting oil. This process also controls the amount of released CO2 as a greenhouse gas in the atmosphere which is known as CO2 sequestration process. However, the mobility of the CO2 inside the hydrocarbon reservoir is higher than the crude oil and always viscous fingering and gravity override problems occur during a CO2 injection. The most common method to overcome these problems is to trap the gas bubbles in the liquid phase in form of aqueous foam prior to CO2 injection. Although, the aqueous foams are not thermodynamically stable, the special care should be considered to ensure about bulk foam preparation and stability. Selection of a proper foaming agent from a large number of available surfactants is the main step in the bulk foam preparation. To meet this purpose, many chemical and crude oil based surfactants have been reported but most of them are not sustainable and have disposal problems. The objective of this experimental study is to employ Lingosulfonate and Alkyl Polyglucosides (APGs) as two sustainable foaming agents for the bulk foam stability investigations and foam flooding performance in porous media. In the initial part, the bulk foam stability results showed that APGs provided more stable foams in compare with Lingosulfonate in all surfactant concentrations. In the second part, the results indicated that the bulk foam stability measurements provide a good indication of foam mobility in porous media. The foaming agent’s concentration which provided the maximum foam stability also gave the highest value of mobility reduction in porous media.
Thread compound "dope?? in the vernacular, has been used routinely in assembling joints of casing and tubing. The practice in almost universal application in the oil and gas industry involves the manual application of the lubricant in a fashion that is rudimentary, non-systematic and unquantifiable. There is evidence presented in this paper that damage to the near-well zone and other unpleasant events may be associated with the thread compound.
This paper presents the results of both laboratory and field investigations quantifying the effects of the dope on near-well damage. During the assembly of tubing and casing a portion of the thread compound is exuded inside and outside the connection and gets access to the well fluids through the tubing and annular space. Studies presented here show that the dope forms a suspension which penetrates and damages the formation. The studies used standard fluid circulation velocities during typical completion operations.
To characterize and quantify the problem, core samples from the El Tordillo field, with different permeabilities were used. The samples were subjected to the circulation of the suspension created by the thread compound and the completion fluid, measuring the change in the core permeability. The work simulated the well conditions during water injection for water injection wells and during acid treatments for producer wells. A significant reduction in permeability, manifested by a fast and a very large increase in pressure, was measured, at the front face of the core sample. The same measurements showed a far smaller impact in the core body suggesting very minor penetration of dope particles.
This paper describes the laboratory and field work, with description of the test protocols, well conditions and laboratory emulation of field conditions that were used.
Stanitzek, Theo (AkzoNobel) | De Wolf, Corine (AkzoNobel) | Gerdes, Steffan (Fangmann Energy Services) | Lummer, Nils R. (Fangmann Energy Services) | Nasr-El-Din, Hisham A. (Texas A&M University) | Alex, Alan K. (AkzoNobel)
Matrix acidizing of high temperature gas wells is a difficult task, especially if these wells are sour or if they are completed with high chrome content tubulars. These harsh conditions require high loadings of corrosion inhibitors and intensifiers in addition to hydrogen sulfide scavengers and iron control agents. Selection of these chemicals to meet the strict environmental regulations adds to the difficulty in dealing with such wells. Recently, a new environmentally friendly chelating agent, glutamic acid -diacetic acid (GLDA), has been developed and extensively tested for carbonate and sandstone formations. Significant permeability improvements have been shown in previous papers over a wide range of conditions. In this paper we evaluate the results of the first field application of this chelating agent to acidize a sour, high temperature, tight gas well completed with high chrome content tubulars.
Extensive laboratory studies were conducted before the treatment, including: corrosion tests, core flood experiments, compatibility tests with reservoir fluids, and reaction rate measurements using a rotating disk apparatus. The treatment started by pumping a preflush of mutual solvent and water wetting surfactant, followed by the main stage consisting of 20 wt% GLDA with a low concentration of a proper corrosion inhibitor. Following the treatment, the well was put on production, and samples of flow back fluids were collected. The concentrations of various ions were determined using ICP. Various analytical techniques were used to determine the concentration of GLDA and other organic compounds in the flow back samples.
The treatment was applied in the field without encountering any operational problems. A significant increase in gas production that exceeded operator expectations was achieved. Unlike previous treatments where HCl or other chelates were used, the concentrations of iron, chrome, nickel, and molybdenum in the flow back samples were negligible, confirming low corrosion of well tubulars. Improved productivity and longer term performance results confirm the effectiveness of the new chelate as a versatile stimulation fluid.
Stationkeeping in ice-covered waters has become a large area of interest forresearch and development in light of heightened interest in Arctic oil and gasexploration. The performance of Dynamic Positioning (DP) control systems forstationkeeping purposes in ice conditions is a difficult challenge fornumerical modeling assessment. Given that full-scale validation data for DP inice operations is often scarce, physical modeling of stationkeeping in iceoffers the best method for assessing the performance of dynamically positionedvessels in these conditions. A series of model tests carried out at theNational Research Council of Canada's Ice Tank facility in August and Septemberof 2011 attempted to observe the effects of various managed ice conditions(i.e. ice floes which have been broken into manageable pieces by an icebreaker) on DP performance. Results from these tests are discussed. Ofparticular interest in this study is the observation of non-linear effects ofvarying ice conditions on DP performance. The use of machine vision-based dataproducts as potential estimators of ice loading is discussed. It is concludedthat simple statistical observations of these conditions will be unable tofully characterize the effects of various ice parameters on performance, andthat investigation into more advanced data products available from machinevision systems may be able to aide in characterizing these effects as well asin the development of models capable of predicting ice loads.