Skrettingland, K. (Statoil ASA) | Ulland, E. N. (Statoil ASA) | Ravndal, O. (Statoil ASA) | Tangen, M. (Statoil ASA) | Kristoffersen, J. B. (Statoil ASA) | Stenerud, V. R. (Statoil ASA) | Dalen, V. (Statoil ASA) | Standnes, D. C. (Statoil ASA) | Fevang, Ø. (Statoil ASA) | Mevik, K. M. (Knutsen Subsea Solutions) | McIntosh, N. (Knutsen Subsea Solutions) | Mebratu, A. (Halliburton) | Melien, I. (Halliburton) | Stavland, A. (Intl Research Inst of Stavanger)
Declining oil production and increasing water cut in mature fields highlight the need for improved conformance control. Here we report on a successful in-depth water diversion treatment using sodium silicate to increase oil recovery at the Snorre field, offshore Norway, utilizing a new operational concept of using a stimulation vessel as a platform for the large-scale injection into a subsea well. A custom modified 35,000 DWT shuttle tanker was employed for the field pilot. This paper describes the vessel preparations and the large-scale interwell silicate injection operation. The operational aspects of the large-scale interwell silicate injection include; identification of injection vessel requirements, major vessel modifications, chemical logistic, general logistics to site, major equipment set-up on vessel, subsea connection, mixing and pumping schedules, onsite QC, and real time monitoring. Experience from these operations and lessons learned are included in this paper.
After the injection of approximately 400,000 Sm3 (113,000 Sm3 preflush, followed by 240,000 Sm3 of sodium silicate gelant and 49,000 Sm3 of postflush fluid) at injection rates up to 4,000 Sm3/d, the injection from the vessel was stopped and the well was put on regular seawater injection. Following more than two years of regular production, transient pressure measurements, tracer testing and water cut data are presented from the ongoing comprehensive data acquisition program. These results demonstrate clearly the achieved in-depth flow diversion through a delayed breakthrough of injected tracers and lower water cut in the relevant production well.
Fracturing fluids are commonly formulated with fresh water to ensure reliable rheology. However, fresh water is becoming more costly, and in some areas, it is difficult to obtain. Therefore, using produced water in hydraulic fracturing has received increased attention in the last few years. A major challenge, however, is its high total dissolved solids (TDS) content, which could cause formation damage and negatively affect fracturing fluid rheology. The objective of this study is to investigate the feasibility of using produced water to formulate crosslinked-gel-based fracturing fluid. This paper focuses on the compatibility of water with the fracturing fluid system and the effect of salts on the fluid rheology.
Produced water samples were analyzed to determine different ion concentrations. Solutions of synthetic water with different amounts of salts were prepared. The fracturing fluid system consisted of natural guar polymer, borate-based crosslinker, biocide, surfactant, clay controller, scale inhibitor, and pH buffer. Compatibility tests of the fluid system were conducted at different cation concentrations. Apparent viscosity of the fracturing fluid was measured using a high-pressure high-temperature rotational rheometer. All rheology tests were conducted at a temperature of 180°F and were conducted according to API 13m procedure with a three-hour test duration. Fluid breaking test was also performed to ensure high fracture and proppant pack conductivity.
Produced water analysis showed a TDS content of 125,000 ppm, including Na, Ca, K, and Mg ion concentrations of 36,000, 10,500, 1,700, and 700 ppm, respectively. Results indicated the potential of produced water to cause formation damage. Therefore, produced water was diluted with fresh water and directly used to formulate the fracturing fluid. Divalent cations were found to be the main source of precipitation, and the reduced amounts of each ion were determined to prevent precipitation. The separate and combined effects of Na, K, Ca, and Mg ions on the viscosity of the fracturing fluid were also studied. Fluid viscosity was found to be significantly affected by the concentrations of divalent cations regardless of the concentrations of monovalent cations. Monovalent cations reduced the viscosity of fracturing fluid only in the absence of divalent cations, and showed no effect in the presence of Ca and Mg ions. Water with reduced concentrations of monovalent and divalent cations showed the most suitable environment for polymer hydration and crosslinking.
This paper contributes to the understanding of the main factors that enable the use of produced water for hydraulic fracturing operations. Maximizing the use of produced water could reduce its disposal costs, mitigate environmental impacts, and solve fresh water acquisition challenges.
Wang, D. (University of North Dakota) | Dawson, M. (Statoil Gulf Services LLC) | Butler, R. (University of North Dakota) | Li, H. (Statoil Gulf Services LLC) | Zhang, J. (University of North Dakota) | Olatunji, K. (University of North Dakota)
With the recent dramatic drop in oil price, production from ultra-tight resources, like the Bakken formation, may drop substantially. Since expenditures for drilling, completion, and fracking have already been made, existing wells will continue to flow, but oil rates will decline—rapidly in many cases. In a low oil-price environment, what can be done to sustain oil production from these tight formations?
We are testing a surfactant imbibition process to recovery oil from shales. We measured surfactant imbibition rates and oil recovery values in laboratory cores from the Bakken shale. After optimizing surfactant formulations at reservoir conditions, we observed oil recovery values up to 10–20% OOIP incremental over brine imbibition. However, whether or not surfactant imbibition will be a viable recovery process depends on achieving sufficiently high oil production rates in a field setting—which requires that we identify conditions that will maximize imbibition rate, as well as total oil recovery. In this paper, we describe laboratory evaluations of oil recovery using different core plugs. These recovery studies involved
(1) surfactant formulation optimization on concentration, salinity and pH, (2) characterization of phase behavior, (3) spontaneous imbibition, and (4) forced imbibition (flooding) with gravity drainage assistance.
In preserved cores, we observed: (1) Formulations using 0.1% surfactant concentration at 4% TDS salinity showed favorable oil recoveries (up to 40% OOIP). (2) Generally, surfactant formulations at optimal concentration and salinity were stable at high temperature (115°C). (3) Injectivity/permeability enhancements up to 75 percent occurred after acidification using acetic acid or HCl. (4) Wettability alteration is the dominant mechanism for surfactant imbibition. Of course, actions that increase fracture width will aid gravity drainage and oil recovery. This information is being used to design and implement a field application of the surfactant imbibition process in an ultra-tight resource.
The application of surfactants to improve oil recovery in conventional reservoirs via wettability alteration and enhancement of spontaneous imbibition has been extensively studied in the literature. However, little work has been performed yet to investigate the interaction of these surfactants with ultra-tight oil-rich shale reservoirs such as Wolfcamp shale. The use of horizontal drilling and massive multistage hydraulic fracturing has made primary oil recovery from these ultra-tight oil-rich shale reservoirs possible. With declining production from existing shale wells, it is essential to explore potential "beyond primary" strategies in shale oil development. This paper analyzes the potential of surfactants in altering wettability and improving the process of spontaneous imbibition in oil rich shales demonstrating nanodarcy range permeability, relevant to stimulation and "beyond primary" chemical EOR applications in shales.
Novel proprietary surfactant blends along with traditional nonionic surfactants were investigated in this study using Wolfcamp shale core samples exhibiting nanodarcy permeability. X-ray diffraction analysis was performed which indicated that Wolfcamp shale has mixed mineralogy, with quartz, calcite, and dolomite acting as the major minerals in varying proportions depending on the interval depth. Contact angle and interfacial tension measurements were performed at reservoir temperature to identify the state of native wettability and the impact of surfactants in altering wettability. Thereafter, spontaneous imbibition experiments were performed using 3D computed tomography methods to understand the improvement in the magnitude of imbibition penetration due to surfactant addition. Contact angle and spontaneous imbibition experiments showed that Wolfcamp shale is intermediate-wet and surfactants have the potential to alter the native wettability to a preferentially water-wet state and improve oil recovery due to enhanced spontaneous imbibition.
Surfactants which altered the wettability significantly, but lowered the interfacial tension only slightly showed the highest oil recoveries due to the creation of strong capillary driven forces directly responsible for effective spontaneous imbibition. The potential of surfactants in altering wettability and improving oil recovery via enhanced spontaneous imbibition in ultra-tight oil-rich shales was verified in this study. The effectiveness of traditional nonionic surfactants in altering wettability and improving oil recovery was found to be comparable to that of novel, more expensive proprietary surfactant blends, and hence, the traditional nonionic surfactants provide a cost effective option for stimulation and EOR applications in Wolfcamp shale. Overall, this paper presents the theory behind surfactant interaction with ultra-tight shales and provides experimental results to validate the viability of surfactant induced improved oil recovery in shales.
Thrasher, David (BP Exploration) | Nottingham, Derek (BP Exploration (Alaska) Inc.) | Stechauner, Bernhard (BP Exploration (Alaska) Inc.) | Ohms, Danielle (BP Exploration (Alaska) Inc.) | Stechauner, Gerda (BP Exploration (Alaska) Inc.) | Singh, Praveen K. (BP America Inc.) | Angarita, Monica Lara (BP Exploration)
Waterflood conformance control due to reservoir heterogeneity is a common challenge to many oilfield developments. This paper describes the application at-scale of a thermally-activated polymer particle system (TAP) for improving waterflood sweep efficiency in the Prudhoe Bay field, Alaska. Since 2004, the technology has been successfully deployed 91 times in Prudhoe Bay Unit on the North Slope of Alaska as part of an approved Enhanced Oil Recovery (EOR) program. A total of 1.6 million gallons of chemical polymer particles have been injected into approximately half of the available waterflood patterns.
Once the polymer particles activate deep in the reservoir, they provide resistance to water flow in the thief (swept) zones. The treatment design workflow applies a thermal model which accounts for the impact of the temperature distribution in the reservoir on activation of the polymer particles. Challenges associated with performance evaluation of the treatment program in a normal operational setting (as opposed to field trial) have been addressed, particularly in relation to interferences to interpretation resulting from the ongoing application of miscible gas EOR in the waterflood areas.
Of the 44 treatments deployed between 2008 and 2012, 22 were sufficiently mature to have performance data which was not adversely impacted by interferences from well work, changes to operating conditions, or miscible gas breakthrough. So far, only one of the 22 patterns has not indicated an incremental oil response, while in two patterns the response had started too recently to be able to extrapolate the overall response magnitude. The analysis showed overall positive responses from the treatments that are competitive with other well work on cost/bbl and project economics. Results from this study provide insights on key controls on waterflood sweep improvements, and inform future candidate selection and optimization of treatment designs.
The production performance analysis was corroborated by wellhead injectivity, repeat pressure fall-off tests, and reservoir modeling. This paper documents a good case history of waterflood sweep improvement.
Improved Oil Reocvery (IOR) technologies may offer a new strategy to improve the initial production (IP) and slow the production decline from oil-rich shale formations. Early implementation of chemical IOR technologies largely have been overlooked during strategic planning of unconventional reservoirs. The purpose of this study is to improve understanding of the dynamic processes of oil displacement by surfactants and to investigate mechanism of how surfactants extract oil. A successful conventional surfactant "huff-n-puff' treatment is described with a focus on any relationship between increased oil production and the surfactant soaking period. Surfactant chemistry has been considered as one of a few ultimate IOR solutions. Despite being well proven as effective chemicals to recover oil from convenetional reservoris, surfactants commonly are used in hydraulic fracturing of unconventional reservoris are just to promote flow back of the injected aqueous fluid over a relatively short time frame. In order to better understand the functionality of surfactants for obtaining favorable oil interaction with both the stimulation fluid and rock matrix, a specifically-designed "oil-on-a-plate" (OOAP) setup and procedure is employed to examine the penetration of surfactant into the oil-film that is adhereing to a solid surface. In addition to the well-recognized spontaneous imbibition and surface wettability alternation processes, surfactant also can gradually penetrate and mobilize oil droplets, resulting in improved oil recovert. If properly selected and designed, the surfactant additives in stimulation/fracturing fluids could have multi-functions towards improving both IP and the longer-term oil production. Besides serving as a demulsifier and flowback enhancer to boost IP, the surfactants could continuously lift-up and mobilize adsorbed oil to increase recoverable oil in place.
Production from liquid-rich shale has become an important contributor to domestic production in the United States, but recovery factors are low. Enhanced Oil Recovery (EOR) methods require injectivity and interwell communication on reasonable time scales. We conduct a feasibility study for the application of recycled lean gas injection to displace reservoir fluids between zipper fracs in liquid-rich shales.
Using new analytical solutions to the Diffusivity equation for arbitrarily-oriented line sources/sinks plus superposition, we analyze the time for inter-fracture communication development, i.e. interference, and productivity index for both classical bi-wing fractures in a zipper configuration and complex fracture networks. We are able to map both pressure and pressure temporal derivative as a function of time and space for production and/or injection from parallel motherbores under the infinite conductivity wellbore and fracture assumption. The infinite conductivity assumption could be later relaxed for more general cases.
We couch the results in terms of geometrical spacing requirement for both horizontal wells and stimulation treatments to achieve reasonable time frames for inter-fracture communication and sweep for parameters typical of various shale plays. We further analyze whether spacing currently considered for primary production is sufficient for direct implementation of EOR or if current practice should be modified with EOR in the field development plan.
Ansari, Arsalan A. (The Petroleum Institute) | Haroun, Mohammed (The Petroleum Institute) | Rahman, Mohammed Motiur (The Petroleum Institute) | Chilingar, George V. (University of Southern California)
The increasing global demand for additional energy requirement forecasted upto 74% in 2030 has made Improved Oil recovery (IOR) at the forefront of oil and gas R&D for the past 4 decades as it helps in the improvement of the hydrocarbon sweep efficiency. In carbonate reservoirs, there is a challenge of having large fractions of unswept oil, mainly due to permeability damage, heterogeneous formation or unfavourable petrophysical properties. Conventional acidizing, though useful in increasing the effective permeability in the near well-bore region, has issues of limited depth of penetration, as acid is consumed and adsorbed early into the formation. However, the application of Electrokinetic Low-concentration acid IOR (EK LCA-IOR), where conventional low-concentration acidizing (LCA-IOR) is coupled with electrokinetic enhanced oil recovery (EK-EOR) [
This study demonstrates an integrated approach using Single Energy Computed-tomography (SECT) scan imaging and Nuclear Magnetic Resonance (NMR) to analyze the compatibility and effectiveness of EK LCA-IOR in carbonate reservoirs through an increase in depth of penetration. Core-flood experiments at Abu Dhabi reservoir conditions conducted on 1-foot core-plug, involved waterflooding followed by LCA-IOR, assisted by electrokinetics in both sequential and simultaneous fashion, identifying optimum conditions (1.2% HCl concentration, 1V/cm voltage gradient).The use of SECT images of core-plug before and after the experiments, confirmed wormhole orientation and propagation length across heterogeneous core-plugs. NMR was used to identify and confirm various reservoir rock types (RRTs)that were tested allowing us to expand the range of optimum current densities and acid concentration for the EK LCA-IOR process to meet the objectives of this study in maximizing displacement efficiency and permeability enhancement.
Findings confirm EK LCA-IOR application resulted in additional 15–35% displacement efficiency beyond the waterflooding limit (60%). In addition, the maximum permeability enhancement of 53% was recorded and made possible using the simultaneous approach. SECT imaging confirmed that the maximum penetration depth of the injected acid was achieved using the simultaneous approach as the enhancement of depth of penetration was 82% and 70% in simultaneous and sequential approach, respectively. Furthermore, NMR results indicate that EK LCA-IOR is promising across heterogeneous formations, which allows us to optimize the process for each unique formation, using the identified operating parameters increasing displacement efficiency by 35% and permeability enhancement by 28%.
EK LCA-IOR may be developed as an environomic technology targeting the reduction of power consumption and acid/water requirement upto 70% as compared to conventional IOR processes. This study takes advantage of integrating imaging capability of SECT & NMR in order to couple particle mobility and zeta potential to assess the performance of EK LCA-IOR compatibility in Abu Dhabi carbonate reservoirs.
Al Ayesh, A. H. (Department of Geoscience and Engineering, Delft University of Technology) | Salazar, R. (Department of Geoscience and Engineering, Delft University of Technology) | Farajzadeh, R. | Vincent-Bonnieu, S. | Rossen, W. R.
Foam can divert flow from higherto lower-permeability layers and thereby improve vertical conformance in gas-injection enhanced oil recovery. Recently,
The effectiveness of diversion varies greatly with injection method. In a SAG (surfactant-alternating-gas) process, diversion of the first slug of gas depends on foam behavior at very high foam quality. Mobility in the foam bank during gas injection depends on the nature of a shock front that bypasses most foam qualities usually studied in the laboratory. The foam with the lowest mobility at fixed foam quality does not necessarily give the lowest mobility in a SAG process. In particular, diversion in SAG depends on how and whether foam collapses at low water saturation; this property varies greatly among the foams reported by Kapetas et al. Moreover, diversion depends on the size of the surfactant slug received by each layer before gas injection. This of course favors diversion away from high-permeability layers that receive a large surfactant slug, but there is an optimum surfactant slug size: too little surfactant and diversion from high-permeability layers is not effective; too much and mobility is reduced in low-permeability layers, too. For a SAG process, it is very important to determine if foam collapses completely at irreducible water saturation.
In addition, we show the diversion expected in a foam-injection process as a function of foam quality. The faster propagation of surfactant and foam in the higher-permeability layers aids in diversion, as expected. This depends on foam quality and non-Newtonian foam mobility and varies with time of injection. Injectivity is extremely poor with foam injection, but is not necessarily worse than waterflood in some effective SAG foam processes
Post-fracturing production data analysis indicates stimulation of some west Texas wells with surfactant additives did not enhance production as high as expected. Analysis of flowback and produced water for surfactant residues revealed 99% of surfactant was retained inside wells (
Literature precedent exists that polyelectrolyte (PET)-based SAs could significantly reduce surfactant adsorption not only onto a variety of outcrop minerals (Carlpool dolomite, calcite, kaolinite, Berea sandstone, Indiana limestone, etc.) and metal oxide nanoparticles, but also unconventional shale formulations in which surface area can be up to 700 m2/g. In this study, the adsorptions of surfactant and SA to proppants were first examined. Results indicate no adsorption was observed to proppant for both surfactants and PET-based SAs. SAs (0.5 to 1 gal/1,000 gal (gpt)) were then injected with surfactant (1 to 3 gpt) at an appropriate ratio into column-packed shale formulations (primarily composed of calcite, dolomite, quartz, illite, pyrite, and plagioclase feldspar) to investigate its effectiveness in controlling surfactant retention caused by adsorption. Laboratory testing revealed injection of 3 gpt mixture of surfactant and SA has a similar adsorption profile (surface tension as a function of time) as 3 gpt surfactant alone based on the dynamic surface tension measurement. Notably, the addition of SAs resulted in lower surface tension and enhanced hydrocarbon solubility; and thus, an improved oil recovery by surfactant was achieved as evidenced by the oil recovery tests. Additionally, 68% friction reduction of the fracturing fluid with surfactant and SA was sufficient for the field operation compared to the guar-based fluid used in the hydraulic fracturing applications.
As a result of the laboratory findings, field trials were executed on a three well pad in the Permian basin (PB). For the first 30 days oil and gas production appeared to be significantly higher than the average production from offset wells in the same area that were previously fractured with the same surfactant.