Qiu, Yue (Missouri University of Science and Technology) | Wei, Mingzhen (Missouri University of Science and Technology) | Geng, Jiaming (Missouri University of Science and Technology) | Wu, Fengxiang (Daqing Xinwantong Chemical Co. Ltd.)
This paper presents the detailed descriptions of successful field application for a high-temperature and high-salinity resistance microgel in a mature reservoir in the northwest part of China. The reservoir with low permeability (230 md) experienced serious vertical and lateral heterogeneity problems, which caused low sweep efficiency and high water-cut (more than 95%). The treatment was designed based on laboratory experiments and experience from previous field application, providing detailed information of mechanism of microgel treatment and project execution. Thermal stability test showed that the microgel could resist the salt concentration up to 230,000 ppm at 125 °C for more than 1 year. From the core analysis, permeability of the long-term water-flooded zone was measured around 1,489 md, proving the evidence that high-permeability zones existed. Pilot test has been done before field application and valuable experience about how to design the injection parameters was provided. According to the information from laboratory experiments and the pilot test, four injection wells associated with nine offset production wells were selected for microgel treatment. For about 10 months treatment, 169 t of microgel was injected by five slugs.
Gradually increased injection pressure suggested that microgel could be placed deeply into the reservoir. The ultimate incremental oil production was approximately 29,635.8 t with the water cut decreasing from 95.3% to 93.1%. Microgel can be successfully used in relative low permeability (230 md) reservoir with harsh conditions for conformance control.
Guo, Hu (China University of Petroleum) | Li, Yiqiang (China University of Petroleum) | Gu, Yuanyuan (China University of Petroleum) | Wang, Fuyong (China University of Petroleum) | Yuliang, Zhang (Research Institute of Xinjiang Oilfield Company, CNPC)
ASP flooding is one of the most promising EOR technologies. Lots of laboratory studies and pilot tests have been finished in Daqing oilfield which is the largest oilfield in China. Comparison of two typical strong alkali ASP (WASP) and weak alkali ASP (SASP) pilots are presented with detained information.
ASP flooding could not only remarkably improve displacement efficiency but also improve sweep efficiency due to the low interfacial tension effect and mobility control technique with help of viscosity enhancement and emulsification effects. The incremental recovery of two ASP was near, while in peak oil production period after the injection took effects, WASP had high oil production rate than SASP. The emulsification effects in weak alkali ASP was weaker than strong one. The chromatographic separation was different in two pilot tests, in which weak alkali ASP had alleviated chromatographic separation. The constitution production sequence was both polymer first, then alkali and finally surfactant. The time gap between surfactant and polymer was about 0.0606 PV for strong alkali ASP, while a respective value of 0.1281PV for weak alkali ASP. Scaling was different and thus anti-scale technique adopted in two pilot tests were a little different. The overall input-output ratio for two tests was different and weak alkali ASP performed much better. Comparison was first made between strong alkali and weak alkali based ASP flooding from field tests perspective. Weak alkali based ASP is proven the development trend.
Three-phase relative permeability can vary greatly from two-phase relative permeability as mechanisms such as flow coupling, double displacement, and layer drainage flow regime play a role in three-phase flow. These are on top of the dependency of three-phase relative permeability on two saturations and saturation path/history. The net result is that it is difficult to model/predict relative permeabilities in three-phase space. In this work, we present three-phase oil relative permeability data measured along 11 saturation paths, in a water-wet consolidated (Berea sandstone) and unconsolidated (sandpack) porous media. These saturation paths cover a wide swath of the three-phase saturation space, providing a better physical understanding of the complete three-phase phase space. Three different oils (crude oil, mineral oil, and n-octane) are used in the experiments; the varying viscosities, spreading coefficients, and composition of the oils allows us to investigate the effect of different drainage mechanisms on relative permeability curves. Our data show that there are significant variations between the curves depending on the media, final water saturation, and fluids. In particular, when the media and fluids are held constant, oil relative permeability can vary an order of magnitude at the same oil saturation, depending on the initial condition and water saturation. We find that within each media, all the curves represent a similar shape, but reach to a different residual saturation. This suggests that residual oil saturation is the key parameter in observed relative permeability differences along different saturation paths. We examine this hypothesis with the most common three-phase relative permeability models, i.e. Saturation Weighted Interpolation, Stone I and II, where we vary residual oil saturation to fit the experimental data. We find that if residual oil saturation is used as a fitting parameter, the models predict experimental data well. Otherwise, without varying residual oil saturation, these relative permeability models perform poorly in predicting experimental data.
Production from tight formation resources leads the growth in U.S. crude oil production. Compared with chemical flooding and water flooding, gas injection is a promising EOR approach in shale reservoirs. A limited number of experimental studies concerning gas flooding in the literature focus on unconventional plays. This study is a laboratory investigation of gas flooding to recover light crude oil from nano-permeable shale reservoirs.
In this work, the N2 flooding process was applied to Eagle Ford core plugs saturated with dead oil. To investigate the effects of flooding time and injection pressure on the recovery factor, two groups of core-flood tests were performed. In group one, flooding time ranged from 1 to 5 days in increments of 1 day; in the other group, the injection pressure ranged from 1,000 psi to 5,000 psi in increments of 1,000 psi. The experimental setup was monitored using X-ray CT that helped to visualize phase flow and estimate the recovery efficiency during the test.
The potential of N2 flooding for improving oil recovery from shale core plugs was examined, and the recovery factor (RF) of each case was presented. The results from group one showed that more oil was produced with a longer flooding time. However, the incremental RF decreased with the increase of flooding time. The oil recovery was significant at the initial period of the recovery process, and a longer flooding time had less effect on extracting more oil. With flooding time constant in 1-day, the results from the second group indicated that RF increased with injection pressure, especially rising pressure, from 1,000 psi to 2,000 psi. The gas breakthrough time became shorter with the increase of injection pressure. The analysis of the CT number showed that the oil recovery process mainly occurred before the gas breakthrough. Once a fluid flow path was established, the injected gas flowed through the limited communication channels; thus, no extra oil could be extracted without increasing the injection pressure. This experimental study illustrates that gas flooding has liquid oil production potential in shale reservoirs.
We study Enhanced Oil Recovery (EOR) through Low Salinity (LS) waterflooding in a brown oil field. LS waterflooding is an emerging EOR technique in which water with reduced salinity is injected into a reservoir to improve oil recovery, as compared with conventional waterflooding, in which High Salinity (HS) brine or seawater are commonly used. The efficiency of this technique can be quantified at the well-scale by a Single Well Chemical Tracer Test (SWCTT), which is an in-situ method for measuring the Remaining Oil Saturation (ROS) after flooding the near-wellbore region with a displacing agent. Two SWCTTs were executed on a sandstone North African field. The tests were realized in sequence with seawater and LS water to evaluate the EOR potential at the well-scale.
Here, we propose the interpretation of these two SWCTTs. They were modeled through numerical simulations because of the presence of several non-idealities in the complex scenario considered. A recently-developed tracer simulator was employed to solve the reactive transport problem. This was used as a fast post-processing tool coupled with a conventional reservoir simulator. Model parameters were estimated within an inverse modeling framework, on the basis of an assisted history matching procedure that exploits the Metropolis Hastings Algorithm (MHA). Results were scaled up on a sector model of the field, and forecast scenarios that consider a field-scale implementation of this technique were defined.
The well-scale displacement efficiency gain associated with LS water, as compared with seawater, was evaluated. It was quantified as a ROS reduction of 8 saturation unit (s.u.), with a P10–P90 range of 3–15 s.u. Reservoir-scale simulations suggest that the associated ultimate oil recovery of the EOR pilot may be increased by 2% with LS water, with a P10–P90 range of 0.7–4.3%.
Overall, the LS EOR potential for a selected field was quantified through a robust and original workflow, based on SWCTT interpretation. This state-of-the-art procedure is now available for further applications. The simulated oil recovery improvement with LS water is promising, and leads the way to the implementation of an inter-well field trial.
Fluorinated benzoic acids (FBA) have been widely used in the oil industry as conservative tracers. However, some of these tracers have been shown to rapidly degrade when tested at temperatures above 121°C within three weeks. Naphthalene sulfonates (NSAs) have been shown to be excellent tracers in geothermal applications. However, a broader study was required to determine tracer conservation in reservoir fluids and formations typically encountered in the oil field.
In this study we compare the oil field industry standard FBA tracers to NSA tracers under dynamic test conditions in the presence of reservoir oil, sandstone, carbonates and clays. We also compare the two sets of tracers under static conditions in the presence of four crude oils and different clay mineralogy to establish tracer conservation. Seven different sodium salts of naphthalene sulfonic acids were tested to determine if the tracers were adsorbed onto natural porous media (reservoir rock) at reservoir conditions. A broad range of conditions were selected to target typical reservoirs encountered. In addition, reservoir rock and a pseudo formation containing 10 Wt.% clay in silica sand were used in sand packs saturated with surrogate brine to ensure the tracer recovery under dynamic conditions.
High pressure liquid chromatography (HPLC-FLD) separation was used for simultaneous detection of seven NSAs while FBAs were analyzed using HPLC-UV. GC analysis of isopropyl alcohol (IPA) was used as a standard against which the others were measured.
Dynamic tracer tests demonstrated that the sodium salts of naphthalene sulfonates behaved similarly to the control, IPA, with none of the tracers adsorbing on to the rock surface or partitioning into the oil phase. The naphthalene sulfonates can be successfully used as conservative tracers most specifically for high temperature applications. NSA tracers are an attractive replacement for conservative FBA tracers in the oil field due to their superior thermal stability, solubility in oil field brine, lower detection limits and cost.
An important factor during the life of a heavy crude reservoir is the oil mobility. It depends on two factors, oil viscosity and oil relative permeability. Two characteristics of nanoparticles that make them attractive for assisting IOR and EOR processes are their size (1 to 100 nm) and ability to manipulate their behavior. Due to their nano-sized structure, nanomaterials have large tunable specific surface areas that lead to an increase in the proportion of atoms on the surface of the particle, indicating an increasing in surface energy. Nanoparticles are also able to flow through typical reservoir pore spaces with sizes at or below 1 micron without the risk to block the pore space. Nanofluids or "smart fluids" can be designed by tuning nanoparticle properties, and are prepared by adding small concentrations of nanoparticles to a liquid phase in order to enhance or improve some of the fluid properties. However the use of nanoparticles and nanofluids for oil mobility has been poorly studied. Hence, the scope of this work is to present the field evaluation of nanofluids for improving oil mobility and mitigate alteration of wettability in two Colombian heavy oil fields; Castilla and Chichimene. Asphaltenes sorption tests with two different types of nanomaterials were performed for selecting the best nanoparticle for each type of oil. An oil based nanofluid (OBN) containing these nanoparticles was evaluated as viscosity reducer under static conditions. Displacement tests through a porous media in core plugs from Castilla and Chichimene at reservoir conditions were also performed. OBN was evaluated to reduce oil viscosity varying oil temperature and water content. Maximum change in oil viscosity is achieved at 122°F and 2% of nanofluid dosage. The use of the nanofluid increased oil recovery in the core flooding tests, caused by the removal of asphaltenes from the aggregation system, reduction of oil viscosity, and the effective restoration of original core wettability. Two field trials were performed in Castilla (CNA and CNB wells), by forcing 200 bbl and 150 bbl of nanofluid respectively as main treatment within a radius of penetration of ~3 ft. Instantaneous oil rate increases of 270 bopd in CNA and 280 bopd in CNB and BSW reductions of ~11% were observed. In Chichimene also two trials were performed (CHA and CHB), by forcing 86 bbl of and 107 bbl of nanofluid as main treatment within a radius of penetration of ~3 ft. Instantaneous oil rate increases of 310 bopd in CHA and 87 bopd in CHB were achieved not BSW reduction has been observed yet. Interventions were performed few months ago and long term effects are still under evaluation. Results look promising making possible to think extending application of nanofluid in other wells in these fields.
Ghasemi, M. (Petrostreamz AS) | Astutik, W. (Petrostreamz AS) | Alavian, S. A. (PERA AS) | Whitson, C. H. (PERA AS/NTNU) | Sigalas, L. (Geological Survey of Denmark and Greenland) | Olsen, D. (Geological Survey of Denmark and Greenland) | Suicmez, V. S. (Maersk Oil & Gas A/S)
This paper presents a novel technique to determine multi-component diffusion coefficients for CO2 injection in a North Sea Chalk Field (NSCF) at reservoir conditions. Constant volume diffusion (CVD) method is used, consisting of an oil-saturated chalk core in contact with an overlying free-space, which is filled with the CO2. The experimental data are matched with an EOS-based compositional model.
Transport by diffusion controls the dynamics of the constant-volume system, together with phase equilibria, allowing a consistent estimation of diffusion coefficients needed to describe the observed changes in system pressure.
We conduct two experiments at reservoir condition: one utilizes a core plug saturated with live-oil, and the other with stock tank oil (STO). Once the experiments are completed, EOS-based compositional simulation is performed to match the experimental data using the oil and gas diffusion coefficients as history matching parameters. The modeling work is conducted with a commercial reservoir simulator using a two dimensional radial grid model to describe the experimental setup.
The experiment utilizes a vertically-oriented core holder with a height of 92 mm and 37.6 mm in diameter. An outcrop chalk core with a sealing sleeve is mounted in the core holder, which has the same diameter and a height of 64.6 mm, thus resulting in an overlying void space. The system is initially saturated with oil at reservoir condition. CO2 is then injected from the top, forming an overlying CO2 chamber, and displacing oil towards the bottom of the core holder. Once CO2 fills the overlying bulk space, the system is isolated with no further injection or production.
The CO2 and oil reach and remain in equilibrium locally at the gas-oil interface throughout the test, initiating and maintaining the diffusion mechanism. Diffusion of CO2 into the oil results in a decreasing pressure, which is the main history matching parameter.
The multi-component diffusion coefficients are found to match the model pressure-time prediction to the experimental data. This suggests the modelling workflow incorporates a representative EOS model and the main transport dynamics controlled by diffusion are being treated properly.
The two main challenges in the modeling are (1) the limitation on setting an appropriately-high permeability for the CO2 chamber, and (2) the reservoir simulator neglects compositional dependency of diffusion coefficients.
Proper simulation of CO2 injection in fractured chalk reservoirs requires the ability to model multi-component diffusion accurately. The proposed CVD-method provides such modeling capabilities. Our modeling and experimental work indicate the novelty of the CVD method to determine the diffusion coefficients of a system where diffusion is the dominant displacement mechanism. The fact that the oil is contained within a low-permeability chalk sample reduces density-driven convection that could result due to non-monotonic oil density changes as CO2 dissolves into the oil.
In 2014, TOTAL performed two Single Well Tracer Tests (SWTT) to evaluate the remaining oil saturation in an offshore high temperature, high salinity carbonate reservoir. The SWTT method has proved to be a reliable way, when carefully programmed, to measure a representative remaining oil saturation without being impacted by near wellbore effects. The objective of these measurements was to evaluate the efficiency of a single well chemical EOR (CEOR) pilot by measuring oil desaturation.
Extensive in-house laboratory work was carried out by TOTAL to lay the foundation for the pre and post CEOR pilot SWTTs. A specific tracer injection skid was internally developed to ease the operations. Specific numerical work was performed to achieve robust designs and interpretations. These simulations, carried out in-house, took into account all major uncertainties highlighted by experimental work. Detailed results from the SWTT preparation phase will be described in the paper.
Results from the baseline SWTT interpretation evidenced excellent quality tracer profiles from the first test and high remaining oil saturation, improving our knowledge on the flooding pattern of this reservoir. Results from the post EOR SWTT showed again a clear response of a remarkable decrease in remaining oil saturation, proving the efficiency of the chemical formulation provided by TOTAL and the envisaged recovery mechanism. Interpretation of these Single Well Tracer Tests also allowed us to evidence a much lower than anticipated reservoir dispersion. These findings highlight the potential of EOR implementations in these carbonate formations.
Lessons learned from these two offshore SWTTs are discussed in this paper, such as the need for specific preparation to tackle the complexity of a high temperature high salinity carbonate reservoir in presence of H2S. TOTAL has shown that such operations can be performed in a strict timeframe while adhering to company safety rules. Careful interpretation of such results is mandatory to validate the success of the single well chemical EOR pilot.