Skauge, T. (CIPR Uni Research) | Skauge, A. (CIPR Uni Research) | Salmo, I. C. (CIPR Uni Research) | Ormehaug, P. A. (CIPR Uni Research) | Al-Azri, N. (PDO) | Wassing, L. M. (Shell Global Solutions International BV) | Glasbergen, G. (Shell Global Solutions International BV) | Van Wunnik, J. N. (Shell Global Solutions International BV) | Masalmeh, S. K. (Shell Global Solutions International BV)
Polymer injectivity is a critical parameter for implementation of polymer flood projects. An improved understanding of polymer injectivity is important in order to facilitate an increase in polymer EOR implementation. Typically, injectivity studies are performed using linear core floods. Here we demonstrate that polymer flow in radial and linear models may be significantly different and discuss the concept in theoretical and experimental terms.
Linear core floods using partially hydrolyzed polyacrylamides (HPAM) were performed at various rates to determine in-situ viscosity and polymer injectivity. Radial polymer floods were performed on Bentheimer discs (30 cm diameter, 2-3 cm thickness) with pressure taps distributed between a central injector and the perimeter production well. The in-situ rheological data are also compared to bulk rheology. The experimental set up allowed a detailed analysis of pressure changes from well injection to production line in the radial models and using internal pressure taps in linear cores.
Linear core floods show degradation of polymer at high flow rates and a severe degree of shear thickening leading to presumably high injection pressures. This is in agreement with current literature. However, the radial injectivity experiments show a significant reduction in differential pressure compared to the linear core floods. Onset of shear thickening occurs at significantly higher flow velocities than for linear core floods. These data confirm that polymer flow is significantly different in linear and radial flow. This is partly explained by the fact that linear floods are being performed at steady state conditions, while radial injections go through transient (unsteady state) and semi-transient pressure regimes.
History matching of polymer injectivity was performed for radial injection experiments. Differences in polymer injectivity are discussed in the framework of theoretical and experimental considerations. The results may have impact on evaluation of polymer flood projects as polymer injectivity is a key risk factor for implementation.
Enhanced oil displacement in a reservoir is highly affected by wettability alterations in conjunction with the lowering of viscosities during steam assisted gravity drainage (SAGD) for bitumen extraction. The impartation of energy in the form of heat to the fluid by injecting steam triggers an alteration to a more water-wet state during SAGD. However, the presence of three distinct phases in the reservoir has implications for the effective modeling of the complex fluid dynamics. Dependency of the relative permeability endpoints on the temperature realized as a function of the introduction of steam is difficult to model. Optimization of any steam process requires simulation in order to adequately characterize years of flow and so a model that is capable of representing three phase flow is necessary. To obtain this a pseudo-two phase relative permeability is proposed that assumes fractional flow theory is valid and treats the experiments as a waterflood.
In this study, experimental recovery data for two SAGD experiments and one hot water flood are empirically matched by manipulating relative permeabilities. The analytical approach implemented allows for the representation of fluid flow in the reservoir by achieving a pseudo-two phase relative permeability that results in comparable performance to the experiments. Waterflooding techniques were utilized which allowed for the negation of the steam phase in the model and so two-phase flow was established.
The sensitivity of the relative permeability curves to temperature change results in the inability to formulate a generic three-phase curve and so the pseudo-two phase curve is valuable for the purpose of simulation. The methodology presented enables the formulation of a simplified relative permeability that is unique to each process used and in that specific location. The model that was established was validated and proven credible by the good match with the experimentally obtained values.
Luo, Haishan (The University of Texas at Austin) | Mohanty, Kishore K. (The University of Texas at Austin) | Delshad, Mojdeh (The University of Texas at Austin) | Pope, Gary A. (The University of Texas at Austin)
Upscaling of unstable immiscible flow remains an unsolved challenge for the oil industry. The absence of a reliable upscaling approach greatly hinders the effective reservoir simulation and optimization of heavy oil recoveries using waterflood, polymer flood and other chemical floods, which are inherently unstable processes. The difficulty in upscaling unstable flow lies in estimating the propagation of fingers smaller than the gridblock size. Using classical relative permeabilities obtained from stable flow analysis can lead to incorrect oil recovery and pressure drop in reservoir simulations.
In a recent study based on abundant experimental data, it is found that the heavy-oil recovery by waterfloods and polymer floods has a power-law correlation with a dimensionless number (named viscous finger number in this paper), which is a combination of viscosity ratio, capillary number, permeability, and the cross-section area of the core. Based upon this important finding as well as the features of unstable immiscible floods, an effective-finger model is developed in this paper. A porous medium domain is dynamically identified as three effective zones, which are two-phase flow zone, oil single-phase flow zone, and bypassed oil (isolated oil island) zone, respectively. Flow functions are derived according to effective flows in these zones. This new model is capable of history-matching a set of heavy-oil waterflood corefloods under different viscosity ratios and injection rates. Model parameters obtained from the history match also have a power-law correlation with the viscous finger number.
The build-up of this correlation contains reasonable physical meanings to quantitatively characterize the upscaled behavior of viscous fingering effects. Having such a correlation enables the estimation of model parameters in any gridblock of the reservoir by knowing the local viscous finger number in reservoir simulations. The model is applied to several heavy-oil field cases with waterfloods and polymer floods with different heterogeneities. Oil recovery in water flooding of viscous oils is overpredicted by classical simulation methods which do not incorporate viscous fingering properly. Simulation results indicate that the new model reasonably differentiates the oil recoveries at different viscous finger numbers, e.g., lower injection rate leads to higher oil recovery. In contrast, classical simulations obtain close oil recoveries under different injection rates or degrees of polymer shear-thinning, which is apparently incorrect for unstable floods. Moreover, coarse-grid simulations using the new model are able to obtain consistent saturation and pressure maps with fine-grid simulations when the correlation lengths are not smaller than the coarse gridblock size. Furthermore, it is well captured by the model that the shear-shinning polymer solution can strengthen the fingering in high-permeability regions due to increased capillary number and viscosity ratio, which is not observed in waterflood. As a whole, the new model shows encouraging capability to simulate unstable water and polymer floods in heavy oil reservoirs, and hence can facilitate the optimization of heavy-oil EOR projects.
Skrettingland, K. (Statoil ASA) | Ulland, E. N. (Statoil ASA) | Ravndal, O. (Statoil ASA) | Tangen, M. (Statoil ASA) | Kristoffersen, J. B. (Statoil ASA) | Stenerud, V. R. (Statoil ASA) | Dalen, V. (Statoil ASA) | Standnes, D. C. (Statoil ASA) | Fevang, Ø. (Statoil ASA) | Mevik, K. M. (Knutsen Subsea Solutions) | McIntosh, N. (Knutsen Subsea Solutions) | Mebratu, A. (Halliburton) | Melien, I. (Halliburton) | Stavland, A. (Intl Research Inst of Stavanger)
Declining oil production and increasing water cut in mature fields highlight the need for improved conformance control. Here we report on a successful in-depth water diversion treatment using sodium silicate to increase oil recovery at the Snorre field, offshore Norway, utilizing a new operational concept of using a stimulation vessel as a platform for the large-scale injection into a subsea well. A custom modified 35,000 DWT shuttle tanker was employed for the field pilot. This paper describes the vessel preparations and the large-scale interwell silicate injection operation. The operational aspects of the large-scale interwell silicate injection include; identification of injection vessel requirements, major vessel modifications, chemical logistic, general logistics to site, major equipment set-up on vessel, subsea connection, mixing and pumping schedules, onsite QC, and real time monitoring. Experience from these operations and lessons learned are included in this paper.
After the injection of approximately 400,000 Sm3 (113,000 Sm3 preflush, followed by 240,000 Sm3 of sodium silicate gelant and 49,000 Sm3 of postflush fluid) at injection rates up to 4,000 Sm3/d, the injection from the vessel was stopped and the well was put on regular seawater injection. Following more than two years of regular production, transient pressure measurements, tracer testing and water cut data are presented from the ongoing comprehensive data acquisition program. These results demonstrate clearly the achieved in-depth flow diversion through a delayed breakthrough of injected tracers and lower water cut in the relevant production well.
Although geochemical reactions are the fundamental basis of the alkaline/surfactant/polymer (ASP) flooding, their importance is commonly overlooked and not fully assessed. Common assumptions made when modeling geochemical reactions in ASP floods include: 1) ideal solution (i.e., using molalities rather than ion activities) for the water and aqueous geochemical species 2) limiting the number of reactions (i.e., oil/alkali and alkali consumptions) rather than including the entire thermodynamically-equilibrated system 3) ignoring the effect of temperature and pressure on reactions 4) local equilibrium ignoring the kinetics. To the best of our knowledge, the significance of these assumptions has never been discussed in the literature. In this paper we investigate the importance of geochemical reactions during alkaline/surfactant/polymer floods using a comprehensive tool in the sense of surfactant/soap phase behavior as well as geochemistry.
We coupled the United States Geological Survey (USGS) state-of-the-art geochemical tool, with 3D flow and transport chemical flooding module of UTCHEM. This geochemical module includes several thermodynamic databases with various geochemical reactions, such as ion speciation by applying several ion-association aqueous models, mineral, solid-solution, surface-complexation, and ion-exchange reaction. It has capabilities of saturation index calculation, reversible and irreversible reactions, kinetic reaction, mixing solutions, inverse modeling and includes impacts of temperature and pressure on reaction constants and solubility products. The chemical flood simulator has a three phase (water, oil, microemulsion) phase behavior package for the mixture of surfactant/soap, oil, and water as a function of surfactant/soap, salinity, temperature, and co-solvent concentration. Hence, the coupled software package provides a comprehensive tool to assess the significance of geochemical assumptions typically imposed in modeling ASP floods. Moreover, this integrated tool enables modeling of variations in mineralogy present in reservoir rocks. We parallelized the geochemistry module of this coupled simulator for large-scale reservoir simulations.
Our simulation results show that the assumption of ideal solution overestimates ASP oil recovery. Assuming only a subset of reactions for a coupled system is not recommended, particularly when a large number of geochemical species is involved, as is the case in realistic applications of ASP. Reservoir pressure has a negligible effect but temperature has a significant impact on geochemical calculations. Although mineral reaction kinetics is largely a function of the temperature and in-situ water composition, some general conclusions can be drawn as follows: to a good approximation, minerals with slow rate kinetic reaction (e.g., quartz) can be excluded when modeling ASP laboratory floods. However, minerals with fast rate kinetic reactions (e.g., calcite) must be included when modeling lab results. On the other hand, in modeling field-scale applications, local equilibrium assumption (LEA) can be applied for fast rate kinetic minerals, whereas kinetics should be used for slow rate kinetic minerals.
Rohilla, Neeraj (TIORCO, a Nalco Champion Company) | Ravikiran, Ravi (Stepan Company) | Carlisle, Charlie T. (Chemical Tracers Inc.) | Jones, Nick (University of Wyoming) | Davis, Marron B. (Sunshine Valley Petroleum Corporation) | Finch, Kenneth B. H. (TIORCO, a Nalco Champion Company)
Sandstone reservoirs containing significant amount of clays (30-40 wt%) with moderate permeability (20-50 mD) provide a unique challenge to surfactant based enhanced oil recovery (EOR) processes. A critical risk factor for these types of reservoirs is adsorption of surfactants due to greater surface area attributed to clays. Clays also have high cation exchange capacity (CEC) and can release significant amounts of di-valents that lead to increased retention of the surfactant. These factors could adversely affect the economics of a flood.
We present a case study where a robust formulation was designed and tested in lab/field for a reservoir located in Wyoming, USA and contains up to 35-40 wt% clays (predominately Kaolinite and Illite). The residual oil saturation is high (Sor=0.4) while the permeability of the formation is between 20-50 mD. The reservoir has been waterflooded historically with low salinity water which has led to formation permeability damage. Due to high levels of clays, adsorption of the surfactant on the rock surface was determined to be between 3-4 mg/g rock by static adsorption tests.
This publication demonstrates how the following challenges have been successfully addressed in the lab as well as in the field in the form of single well chemical tracer test (SWCTT).
Designed a robust alkaline-surfactant-polymer (ASP) formulation that showed ultra-low interfacial tension (IFT) values and aqueous solubility remains soluble in the aqueous solution over a broad range of salinity. Mitigated surfactant adsorption issues to make the cEOR solution economic. A sacrificial agent was identified that acted synergistically with alkali and also did not alter the optimum salinity of the formulation. Performed restored state core analysis using the available damaged core material. The main challenge being restoration of the coreplugs to current reservoir conditions for coreflood experiment without causing additional formation damage due to injection of low salinity formation brine. Designed a flood that utilized a pre-flush to provide a favorable salinity gradient and to inject sacrificial agent ahead of the surfactant front. Performed polymer screening to select right molecular weight of polymer so that the right balance of mobility control and injectivity in the reservoir can be obtained.
Designed a robust alkaline-surfactant-polymer (ASP) formulation that showed ultra-low interfacial tension (IFT) values and aqueous solubility remains soluble in the aqueous solution over a broad range of salinity.
Mitigated surfactant adsorption issues to make the cEOR solution economic. A sacrificial agent was identified that acted synergistically with alkali and also did not alter the optimum salinity of the formulation.
Performed restored state core analysis using the available damaged core material. The main challenge being restoration of the coreplugs to current reservoir conditions for coreflood experiment without causing additional formation damage due to injection of low salinity formation brine.
Designed a flood that utilized a pre-flush to provide a favorable salinity gradient and to inject sacrificial agent ahead of the surfactant front.
Performed polymer screening to select right molecular weight of polymer so that the right balance of mobility control and injectivity in the reservoir can be obtained.
Alkaline-surfactant-polymer (ASP) flooding of a viscous oil (100 cp) is studied here in a two-dimensional (2D) sand pack. An ASP formulation was developed by studying the phase behavior of the oil with several alkaline-surfactant formulations. The effectiveness of the ASP formulation was validated in a 1D sand pack by conducting a water flood followed by a stable ASP flood. Reservoir sand was then packed into a 2D square steel cell similar to a quarter five-spot pattern. Several ASP floods were then conducted in this 2D cell to study both the displacement and sweep efficiency of ASP floods. First, the polymer concentration was varied to find an optimum polymer concentration. Then the waterflood extent was varied (0–1 PV) after which the ASP flood was initiated. The oil recovery, oil cut, effluent concentration and pressure drop were monitored during the floods. The tertiary ASP flood was very effective in 1D and validated the ASP formulation. The 2D tertiary ASP flood also recovered most of the oil (~98% of OOIP) when the ASP slug viscosity exceeded the oil viscosity, but the pressure gradients were high at ~ 1ft/d injection. When the ASP slug viscosity was lowered to ~1/3 of oil viscosity, oil recovery dropped slightly to 90% OOIP. However, it also decreased the pressure gradient 5 times, which would give good flow rates in the field conditions. As the extent of waterflood preceding ASP got shorter, the oil was recovered faster (for the same pore volumes injected), but the pressure gradient was higher for the ASP flood than the water flood. The ultimate recovery was independent of the extent of waterflood.
SmartWater flooding through injection of chemistry optimized waters by tuning individual ions is recently getting more attention in the industry for improved oil recovery in carbonate reservoirs. Most of the research studies described so far in this area have been limited to studying the interactions at rock-fluids interfaces by measuring contact angles, zeta potential, and adhesion forces. The other widely reported interfacial tension data at oil-water interfaces do not consider the formation of interfacial monolayer and the interfacial tension is estimated as an average parameter relying on the properties of two individual bulk phases. As a result, such measurements have serious shortcomings to provide any details on complex microscopic scale interactions occurring directly at the interface between crude oil and water to understand the SmartWater flood recovery mechanism.
In this study, two novel interfacial instruments of interfacial shear rheometer and surface potential sensor were used to study microscopic scale interactions of various individual water ions at both air-water and complex crude oil-water interfaces. The measured interfacial rheology data indicated totally different interfacial behavior at crude oil-water interface when compared to air-water interface due to presence of crude oil functional groups. Viscous dominated response was observed at crude oil-water interface for all brine compositions. These interfaces behaved like a viscous fluid without exhibiting viscoelastic solid like properties. Lower interfacial viscous modulus was observed for certain key ions such as calcium, magnesium, and sodium. The interfacial viscous modulus was found to be substantially much higher for sulfates, besides exhibiting some elasticity. The surface potential was gradually decreased by replacing seawater with calcium only brine. The better surface activity with seawater can be attributed to adsorption of more key water ions at the surface.
The interesting results observed with certain water ions at fluid-fluid interfaces are expected to work in tandem with rock-fluids interactions to impact oil recovery in SmartWater flood. At first, they play a role to control the accessibility of active water ions to approach the rock surface, interact with it and subsequently alter wettability. Next oil droplets adhering to the rock surface will be detached and released due to favorable interactions occurring at rock-fluids interfaces. The interfacial film between oil and water can then quickly be destabilized due to less viscous interfaces observed with certain ions to promote drop-drop coalescence and easy mobilization of released oil droplets. This coalescence process is sequential and it would continue until the formation of small oil bank.
This is the first study that showed added importance of fluid-fluid interactions in SmartWater flood by using direct measurements on individual water ions at crude oil-water interface. In addition, a new oil recovery mechanism was proposed by combining both the interactions occurring at fluid-fluid and rock-fluids interfaces. The new fundamental knowledge gained in this study will provide an important guidance on how to synergize water ion interactions at fluid-fluid interfaces with those at rock-fluids interfaces to optimize oil recovery from SmartWater flood.
Wang, D. (University of North Dakota) | Dawson, M. (Statoil Gulf Services LLC) | Butler, R. (University of North Dakota) | Li, H. (Statoil Gulf Services LLC) | Zhang, J. (University of North Dakota) | Olatunji, K. (University of North Dakota)
With the recent dramatic drop in oil price, production from ultra-tight resources, like the Bakken formation, may drop substantially. Since expenditures for drilling, completion, and fracking have already been made, existing wells will continue to flow, but oil rates will decline—rapidly in many cases. In a low oil-price environment, what can be done to sustain oil production from these tight formations?
We are testing a surfactant imbibition process to recovery oil from shales. We measured surfactant imbibition rates and oil recovery values in laboratory cores from the Bakken shale. After optimizing surfactant formulations at reservoir conditions, we observed oil recovery values up to 10–20% OOIP incremental over brine imbibition. However, whether or not surfactant imbibition will be a viable recovery process depends on achieving sufficiently high oil production rates in a field setting—which requires that we identify conditions that will maximize imbibition rate, as well as total oil recovery. In this paper, we describe laboratory evaluations of oil recovery using different core plugs. These recovery studies involved
(1) surfactant formulation optimization on concentration, salinity and pH, (2) characterization of phase behavior, (3) spontaneous imbibition, and (4) forced imbibition (flooding) with gravity drainage assistance.
In preserved cores, we observed: (1) Formulations using 0.1% surfactant concentration at 4% TDS salinity showed favorable oil recoveries (up to 40% OOIP). (2) Generally, surfactant formulations at optimal concentration and salinity were stable at high temperature (115°C). (3) Injectivity/permeability enhancements up to 75 percent occurred after acidification using acetic acid or HCl. (4) Wettability alteration is the dominant mechanism for surfactant imbibition. Of course, actions that increase fracture width will aid gravity drainage and oil recovery. This information is being used to design and implement a field application of the surfactant imbibition process in an ultra-tight resource.
Microemulsion properties significantly impact any EOR process that relies on surfactants or soaps to generate ultralow interfacial tension to displace trapped oil. Unfavorable microemulsion viscosity can lead to high chemical retention, low oil recovery, and overall unfavorable performance across all modes. Controlling microemulsion properties is important in conventional approaches like surfactant-polymer (SP) and alkaline-surfactant-polymer (ASP) flooding, in addition to new applications like gravity stable displacements, spontaneous imbibition in fractured carbonates and unstable floods of viscous oil. Despite the central importance, microemulsion viscosity and rheology remain poorly understood.
This paper describes the results of an extensive experimental microemulsion study. We evaluated the effect of polymer on microemulsion viscosity in different microemulsion phase types (i.e. oil in water, bi-continuous, water in oil emulsions). We measured microemulsion viscosities across a broad salinity range for several crudes from light (API >30°) to heavy oils (API<14°) and observed Newtonian rheology for all phase types. The effect of cosolvents on microemulsion viscosity was also evaluated. Finally, we evaluated microemulsions with and without alkali to help understand potential differences between ASP and SP microemulsions.
We include many observations consistent with earlier literature using recently developed surfactants and report the microemulsion viscosity details for many high performance surfactant formulations across a wide range of conditions. We have also describe several observations, including polymer decreasing the required time to achieve equilibrium in microemulsion pipettes and the qualitative change in microemulsion behavior with and without polymer in Windsor Type III microemulsions.