Zhu, Youyi (Research Inst. Petr. Expl/Dev) | Hou, Qingfeng (Research Institute of Petroleum Exploration & Development, CNPC) | Weng, Rui (Research Inst. Petr. Expl/Dev) | Jian, Guoqing (Research Institute of Petroleum Exploration & Development, CNPC) | Luo, Yousong (Research Institute of Petroleum Exploration & Development, CNPC) | Li, Jianguo (Research Institute of Petroleum Exploration & Development, CNPC)
For mature oil fields, foam flooding is an attractive chemical EOR technique and many pilot tests have been carried out in China. The performance of foam flooding pilot tests and its affect factors on oil recovery was discussed in this paper. The development trend and key technologies of foam flooding technique are pointed out.
Eighteen foam flooding pilot tests have been carried out in China from 1994 to 2010. Good performance have achieved in sixteen pilot tests. Through effects analysis of the pilot tests, three main aspects are concluded for affecting the performance of foam flooding tests. First, the characteristics of target reservoirs influence effects of foam flooding tests. The performance of foam flooding in higher oil viscous reservoirs is better than that in light oil reservoirs. The reservoir temperature and formation water salinity also influences the effects of foam flooding. Secondly, the chemical formula of foam solution and the size of slug influence the performance of foam flooding. The stability of foam formula influences the effects of foam flooding greatly. With the same amount of surfactant solution, the effect of high concentration small-sized slug is better than that in low concentration large-sized slug. Last, the injection method and gas liquid ratio can directly influence the foam performance in the reservoir, gas and liquid mixing injecting model is better than surfactant solution-alternation-gas (SAG) injection, and reasonable gas liquid ratio is important for guarantee good effects of foam flood.
At present, the trend of foam flooding in China is from nitrogen foam flooding and natural gas foam flooding to air foam flooding. The key technologies of foam flooding are the development of high stable foam formula with oil tolerance, salt and temperature resistance, good injection method and reasonable injection parameter etc.
This paper focuses on the design, the operation and the laboratory work needed for performing a successfull Single Well Tracer Test (SWTT) campaign in the Handil mature field Indonesia. Three tests have been performed in different waterflooded reservoirs to assess the repartition of Remaining Oil Saturation (ROS) in the field.
An extensive laboratory work has been performed prior to tests to screen chemicals that could be used and then to measure the two main parameters needed for the design of the tests: the partitioning coefficient of the primary tracer between water and oil (Kd) and the hydrolysis reaction rate (kH) of the primary tracer into the water. Measurements were performed at reservoir temperature and pressure conditions using recombined live oil sample and recombined brine with respect to the salinity of each reservoir. Results indicate very low discrepancy of Kd value between reservoirs (4 to 5), while kH show a strong linear dependency with salinity (from 0.12 to 0.45 day-1). To take into account the presence of trapped gas saturation, we measured also the partitioning coefficient of AcOET between the water and the gas phase at reservoir pressure and temperature. As expected the Kd water/gas was low compare to the water/oil with a value of 0.5.
Tests were performed in parallel after the installation and the calibration of laboratory equipments and the commissionning of the injection barge. The tracer profiles quality recorded from the three tests was very good with high tracer recovery and low scattering data. However the interpretation was challenging, and numerical simulation was necessary to handle non ideal phenomenan occurring during these tests and to get reliable ROS estimation. The ROS values range between 20-30% which allows moving forward in the identification of potential EOR reservoir candidates and locations of future pilot zones for the more promising EOR processes.
Liu, Xincang (No.4 Oil Production Company of Daqing Oilfield) | Zhang, Dong (No.4 Oil Production Company of Daqing Oilfield) | Ding, Jian (No.4 Oil Production Company of Daqing Oilfield) | Ran, Fajiang (No.4 Oil Production Company of Daqing Oilfield) | Zhao, Mingchuan (No.4 Oil Production Company of Daqing Oilfield) | Li, Shiyong (No.4 Oil Production Company of Daqing Oilfield)
It's very important to evaluate layered producing performances at different stages in the course of oilfield development, but due to limitations of monitoring well conditions and logging expenses, it is difficult to comprehensively and systematicly monitor all the producers, and this will bring troubles to adjustments and evaluations during oil field development. To solve this problem, the Chromatographic Fingerprint technique is introduced to monitor layered producing performances in test area F which has four target zones in Daqing Oilfied. After response of alkaline-surfactant-polymer (ASP) flooding, screw pumps are adopted to some producers to minimize scaling in F area where producing profile surveys for annulus wells aren't adaptable to mornitor the layed producing status. Pre-test in lab shows that the Chromatographic Fingerprint technique is feasible for the four individual test zones for there are distinct chromatographic fingerprint differences, and ASP injected solution has less influences on fingerprints. A fuzzy interpretation template has been successfully set up for commingled 4-6 layers production numerical simulation by using EPB neural network model, and relative errors can be controlled below 10%. The technique has been applied to the producers for 180 times. In-situ test results are stable and correspond to the static information of lays. It indicates that the Chromatographic Fingerprint technique is suitable for monitoring individual zone producing performances of ASP flooding. The results from the fuzzy interpretation template have provided powerful data to re-recognize the connectivity of heterogeneous reservoir between injectors and producers. It can be applied to producers whose producing intervals belong to the fuzzy interpretation template. The oil production proportion of per lay's can be easily achieved after the sample from the well fluid is analysed with chromatography and calculated with the fuzzy interpretation template. The technique has proved to be economical and it is not astricted by well conditions, so it can play an important role to guide development programs' adjustments and evaluations in oilfields.
This paper discusses a structured combination of procedures used to investigate polymers for EOR application with the focus on performance, compatibility with production chemicals and phase behaviour. This approach allows for early identification of risks and points to further work necessary for mitigation before field implementation. The case studied here was a system with total dissolved solids (TDS) of 80000 mg/l and temperature requirements of 40 to 70 oC. Effective screening of polymers has benefited from dissolution/viscosity, thermal stability and filtration tests. At lower temperatures (40 oC), polymers were shown to be fit-for-purpose for the conditions evaluated. All polymers showed loss of viscosity with some leading to complete viscosity loss at increased temperatures. This is the result of hydrolysis and interaction with the divalent cations present in the make-up synthetic brine. In-situ viscosity allowed for identification of phase behaviour effects which could affect injectivity (difference in apparent and rheometer viscosity). For the best performing polymer the presence of corrosion and scale inhibitors did not affect viscosity. No detrimental effects on corrosion inhibition and water in oil emulsions were observed. Increases in oil in water with potential fouling/deposition was identified for future study.
EOR technology has been applied on many projects globally with variable success. It shows great potential for offshore heavy oil with oil recovery low in life span of platform (general less than 30% by water flooding). About 60-70% oil is remained in the formation after water flooding, and for offshore heavy oil reservoir, more oil (about 80%) is remained by the end of the platform life.  It becomes more important to achive high recovery before abandoning the platform and the oilfields with lots of oil left in reservoir. With recovery increasment of 5-10% by EOR methods, the reserve will increase greatly, which means an order of magnitude of hundreds of million-tons oilfield is discovered without increase any exploration investment.
Surfactant-polymer (SP) flooding was a potential enhanced oil recovery (EOR) technology that was more powerful than the polymer flooding. And it was test or applied successfully in some high or extra-high WCT onshore oilfields of Shengli oilfields (SINOPEC), Daqing oilfields (CNPC) in china. The paper presents a filed EOR test case of offshore heavy oilfield oilfield by SP.
Konishi, Yusaku (Japan Oil, Gas and Metals National Corporation) | Takagi, Sunao (Japan Oil, Gas and Metals National Corporation) | Farag, Sherif (Sclumberger) | Ha, Vo Viet (Japan Vietnam Petroleum Co., Ltd.) | Hatakeyama, Atsushi (JX Nippon Oil & Gas Exploration Corporation) | Trung, Phan Ngoc (Vietnam Petroleum Institute) | Son, Le Ngoc (PetroVietnam)
The application of the Carbon Dioxide Enhanced Oil Recovery (CO2-EOR) to an offshore oilfield in Vietnam has been investigated through an international joint study between Japan and Vietnam since 2007. In order to reduce and mitigate uncertainties and risks for future field scale application, a CO2-EOR pilot test was conducted in the Rang Dong field, offshore Vietnam in 2011.
The pilot test was conducted as a single-well "Huff-n-Puff?? operation which was designed to minimize the test duration, required CO2 volume to observe the meaningful CO2-EOR effects and to reduce the risk of corrosion to the existing facility. Over 100 tons of CO2 were successfully injected into the Lower Miocene sandstone reservoir and the well was flowed back after two days of soaking time. Various parameters were monitored including production rate, bottom-hole pressure and production fluid properties. To investigate the CO2-EOR effects and for the purpose of monitoring the reservoir fluid saturation change, cased hole pulsed neutron saturation logging was carried out during every stage of the test. These logging operations and their timing were carefully designed to avoid any possibility of fluid contamination and to minimize operation time.
Through the analysis of the acquired logs, vertical contrast of preferential CO2 injection, zonal oil saturation change, oil saturation change with time within single run, etc., were clearly identified. These observations played important roles in evaluating the CO2-EOR effect in detail by comparing them with the reservoir simulation prediction.
In this paper the detailed design for the reservoir fluid saturation monitoring, observed results and three-phase fluid saturation changes wtih time are discussed.
Among the different Enhanced Oil Recovery methods being implemented in the matured fields of Malaysia, Immiscible Water Alternating Gas (iWAG) appears to be the most viable option. However, reduction in well injectivity and productivity would be very harmful to this process and render it ineffective. Therefore, extensive laboratory testing, interpretation and integration have been performed to reach the conclusions and recommendations presented in this paper.
The target reservoirs in the Bokor are made up of unconsolidated and very heterogeneous rock with high permeability streaks. The mineralogy of the target reservoirs shows over 10% of clay, with abundance of kaolinites and illites which tend to cause fines migration and mixed layer illites/smectite which can swell. Therefore special handling of core samples is necessary for the laboratory testing; this includes flow through cleaning and critical point drying.
The aim of the study is to establish the potential mechanisms of formation damage during the iWAG progress and determine preventive, mitigative measures and provide guidelines for treatment if damage occurs. The main focus is on formation damage by fines migration, dirty injection fluids (Mechanically induced damage) and clay swelling and de-flocculation (Chemical induced damage - fluid rock interaction) effect to Bokor field. The laboratory tests performed includes capillary suction time, filtration level test, critical velocity and fines stabilizer test, constant rate injectivity test and formation damage by iWAG injection test.
Key areas of interesting findings include (1) Potential formation damage mechanism during the iWAG process (2) Strategies to prevent damage and improved injectivity, (3) Recommended treatment frequency based on injection half-life established in this study and (4) Field monitoring strategies.
Chemical EOR projects were very active during 1980?s, however, during 90?s the interest in chemical EOR has fallen due to the low oil prices and also technical challenges that the methods poses. While surfactant flooding has difficult design considerations of chemicals, large capital requirements and is very sensitive to local reservoir heterogeneities, alkali can react strongly with minerals in the connate water and reservoir rocks may adversely impact the process. This complex process is yet to be understood. If the field is offshore, chemical EOR becomes even more challenging due to sophisticated logistics, incremental costs, highly deviated wells, larger well spacing and limited well slots on the platform. However, recently there has been a renewed interest in chemical flooding mainly due to valuable insights gained through chemical floods done in the past and better technical understanding of the processes and favorable economic conditions
For robust production forecasts, various uncertainties due to complex chemical processes should be quantified thoroughly. Some of the important uncertainties for full field production forecasts are chemical adsorption on rock surface, interfacial tension (IFT) and residual oil saturation reduction by chemical. Proper coreflood experiments are critical to reduce these uncertainties. Careful matching of coreflood experiments in numerical simulations is also important which provides key inputs for full field forecast. Another important element in the successful commercial application for chemical EOR process is a well-designed pilot. After the completion of pilot, the results should be carefully matched in the simulation model. Once satisfactory match is obtained, the key step would be to upscale the results to the full field level.
Discussed in this paper are the impact of some of these uncertainties and the method used to reduce them. In this paper the workflow and key tasks in dealing with the simulation of chemical EOR process elements like residual oil saturation, IFT reduction and adsorption parameters are discussed. The results show that the incremental oil is very sensitive to the various simulation inputs.
Trigos, Erika Margarita (Ecopetrol) | Vega Moreno, Sandra Milena (Corporacion Natfrac) | Rodriguez-Paredes, Edwin (Ecopetrol SA) | Rivera de la Ossa, Juan Eduardo (Ecopetrol SA) | Naranjo-Suarez, Carlos Eduardo (Ecopetrol S.A.)
In the design phase of a pilot project for Enhanced Oil Recovery, more commonly referred as EOR, is important the prediction of the results by either numerical simulation or analytical modeling. Those tools are useful for the determination of the minimum conditions necessary for the implementation of the recovery method as well as to determine the feasibility of the project.
The more complexity degree of the process the more accurate the fluid model require. For example, to represent the steam injection process, any viscosity curve representing the behavior of known relative permeability curves with temperature is enough. Moreover, Enhanced Oil Recovery-EOR methods as in situ combustion, gas injection or miscible solvent injection (alone or assisted vapor) fluid require a more complex model representing all consistently appropriate physical-chemical changes that occur in the crude blend with a foreign agent.
The development of a numerical model of fluid to represent of injection processes of steam assisted with solvent. This model requires a previous experimental evaluation, which should include PVT characterization of solvent and oil, viscosity curves and miscibility conditions. Once they are developed in the lab tests, it should load the information obtained in a fluid modeling software, where the dead oil, live oil, blend live oil and solvent must be adjusted using equations of state. In this case, the equation of state that best represents the behavior of heavy oil and solvent is Peng Robinson. The most important matching parameters are: critical temperature and critical pressure, although it should be given special treatment with the binary interaction coefficients. Finally be obtain the equilibrium constants and viscosity tables, maintaining minimum allowable error of less than 5% compared to the laboratory data, which is important to reduce the uncertainty associated with the behavior of fluids.
This paper presents a detailed methodology to represent numerically the behavior of fluids in a steam injection process enhanced with solvent in heavy oil reservoirs, applied to a Colombian field.
Shiau, Bor Jier Ben (University of Oklahoma) | Hsu, Tzu-Ping (University of Oklahoma) | Lohateeraparp, Prapas (University of Oklahoma) | Rojas, Mario R. (University of Oklahoma) | Budhathoki, Mahesh (University of Oklahoma) | Raj, Ajay (University of Oklahoma) | Wan, Wei (University of Oklahoma) | Bang, Sangho (University of Oklahoma) | Harwell, Jeffrey H. (University of Oklahoma)
Reservoirs containing very high total dissolved solids and high hardness make the design of a surfactant polymer (SP) flood extremely difficult because surfactant tends to precipitate and separate under these conditions. Beside divalent ions, Ca2+, Mg2+, presence of iron in the brine can be a challenging issue. Different surfactant formulations are evaluated and incorporate cosurfactants and co-solvents which minimize viscous macroemulsions, promote rapid coalescence under Winsor Type III conditions, and stabilize the chemical solution by reducing precipitation and phase separation. The optimal surfactant formulations were further evaluated in one-dimensional sand packs and coreflood tests using Berea sandstone, reservoir oils, and brines at reservoir temperatures. Using similar injection protocols, 3 pore volumes of surfactant-only system, experimental results show the oil recovery ranging from 45 % to 70% of the residual oil (Sor) after water flooding. The level of surfactant loading is less than 0.5 wt%. A single-well test was conducted to confirm laboratory results in situ in the presence of high-salinity formation water containing 102,300 mg/L total dissolved solids (TDS). The aim of ongoing test is to confirm the effectiveness of the high-salinity surfactant-only formulation (0.46 wt% of surfactant). In this effort, we plan to conduct multiple single-well tests at different wells to minimize the design risks involved for the surfactant pilot test. A pilot test at a sandstone reservoir is scheduled to be performed in July of 2013 to further evaluate the effectiveness of surfactant formulation and address technical issues related to scale-up.