Viscosity and Density are important physical parameter of crude oil, closely related with the whole processes of production and transportation, and are very essential properties to the process design and petroleum industries simulation. As viscosity increases, a conventional measurement becomes progressively less accurate and more difficult to obtain. According to the literature survey, most published correlations that are used to predict density and viscosity of heavy crude oil are limited to certain temperatures, API values, and viscosity ranges. The objective of present work is to propose accurate models that can successfully predict two important fluid properties, viscosity and density covering a wide range of temperatures, API, and viscosities. Viscosity and density of more than 30 heavy oil samples of different API gravities collected from different oilfield were measured at temperature range 15oC to 160oC (60oF to 320oF), and the results were used to ensure the capability of proposed and published correlations to predict the experimental viscosity and density data. The proposed correlation can be summarized in two stages. The first step was to predict the heavy oil density from API and temperature for different crudes. The predicted values of the densities were used in the second step to develop the viscosity correlation model. A comparison of the predicted and actual viscosities data, concluded that the proposed model has successfully predict all data with average relative errors of less than 12% and with the correlation coefficient R2 of 0.97, and 0.92 at normal and high temperatures respectively. Meanwhile, the results of most of the available models has an average relative error above 40%, with R2 values between 0.19 to 0.95. These comparisons were made as a quality control to confirm the reliability of the proposed model to predict density and viscosity values of heavy crudes when compared with other models.
Sanyal, Tirtharenu (Kuwait Oil Company) | Al-Hamad, Khairyah (KOC) | Jain, Anil Kumar (KOC) | Al-Haddad, Ali Abbas (KISR) | Kholosy, Sohib (KISR) | Ali, Mohammad A.J. (Kuwait Inst. Scientific Rsch.) | Abu Sennah, Heba Farag (Kuwait Oil Company)
Improved oil recovery for heavy oil reservoirs is becoming a new research study for Kuwaiti reservoirs. There are two mechanisms for improved oil recovery by thermal methods. The first method is to heat the oil to higher temperatures, and thereby, decrease its viscosity for improved mobility. The second mechanism is similar to water flooding, in which oil is displaced to the production wells. While more steam is needed for this method than for the cyclic method, it is typically more effective at recovering a larger portion of the oil.
Steam injection heats up the oil and reduce its viscosity for better mobility and higher sweep efficiency. During this process, the velocity of the moving oil increases with lower viscosity oil; and thus, the heated zone around the injection well will have high velocity. The increase of velocity in an unconsolidated formation is usually accompanied with sand movement in the reservoir creating a potential problem.
The objective of this study was to understand the effect of flowrate and viscosity on sand production in heavy oil reservoir that is subjected for thermal recovery process. The results would be useful for designing completion under steam injection where the viscosity of the oil is expected to change due to thermal operations.
A total of 21 representative core samples were selected from different wells in Kuwait. A reservoir condition core flooding system was used to flow oil into the core plugs and to examine sand production. Initially, the baseline liquid permeability was measured with low viscosity oil and low flowrate. Then, the flowrate was increased gradually and monitored to establish the value for sand movement for each plug sample. At the end of the test, the produced oil containing sand was filtered for sand content.
The result showed that sand production increased with higher viscosity oil and high flowrate. However, sand compaction at the injection face of the cores was more significant than sand production. In addition, high confining pressure contributes to additional sand production. The average critical velocity was estimated ranged from 18 to 257 ft/day for the 0.74 cp oil, 2 to 121 ft/day for the 16 cp oil, and 1 to 26 ft/day for the 684 cp oil.
A live oil sample was subjected to a solid detection system (SDS) to measure asphaltene onset point (AOP) at 3850 psi, and asphaltene content of 1.3%. A high-resolution digital camera was used to measure asphaltene particle size distribution. The result showed that asphaltene particles were not uniform in size, but has a normal distribution of 100-120 µm. Asphaltene reversibility to dissolved back into the oil with increasing pressure was only 35% of the original deposition. Two core samples were examined for formation damage due to asphaltene deposition. A Low permeability core showed significant permeability reduction exceeding 50% of its baseline permeability, and the higher permeability core showed less permeability decline, even with the same asphaltene precipitation.
Shubham, Agrawal (Texas A&M University at Qatar) | Martavaltzi, Christina (Texas A&M University at Qatar) | Dakik, Ahmad Rafic (Texas A&M University at Qatar) | Gupta, Anuj (Texas A&M University at Qatar)
It is well known that the majority of carbonate reservoirs are neutral to oil-wet. This leads to much lower oil recovery during waterflooding since there is no spontaneous imbibition of water in heterogeneous reservoir displacement. It has been verified by a number of researchers that Adjustment of ion concentration in brine solutions, or adding surfactant solutions can enhance the oil recovery by altering the wettability. In the published literature, contact angle studies usually refer to measurement on calcite crystals and there are no results for the contact angle of carbonate porous media representative of reservoir rocks. Moreover, there are few studies on the effect of non-ionic surfactants, compared to those for ionic surfactants. Understanding the effect of various ions and their concentration in the injection brine on the wettability of the Limestone outcrop core samples is the first step for tailoring of the optimum injection brine. This will be followed by a study of the effect of surfactant on the wettability of calcite crystal samples. The evaluation of the results may provide guidelines for the design of injection brines for efficient enhanced oil recovery from carbonate reservoirs.
In this work, a procedure is established for the measurement of the contact angle on limestone outcrop core samples. Results showed that, at atmospheric conditions, low salinity CaCl2 solution induced the most significant improvement on the wettability of the outcrop sample. Moreover, among all the non-ionic surfactants studied, only the presence of the two first members of the 15S analogous series might lead to a slight decrease of the contact angle.
The significance of exploring deep and ultra-deep wells is increasing rapidly to meet the increased global demands on oil and gas. Drilling at such depth introduces a wide range of difficult challenges and issues. One of the challenges is the negative impact on the drilling fluids rheological properties when exposed to high pressure high temperature (HPHT) conditions and/or becoming contaminated with salts, which are common in deep drilling or in offshore operations.
The drilling engineer must have a good estimate for the values of rheological characteristics of a drilling fluid, such as viscosity, yield point and gel strength, and that is extremely important for a successful drilling operation. In this research work, experiments were conducted on water-based muds with different salinity contents, from ambient conditions up to very elevated pressures and temperatures.
In these experiments, water based drilling fluids containing different types of salt (NaCl and KCl) and at different concentrations were tested by a state-of-the-art high pressure high temperature viscometer. In this paper, the effect of different electrolysis (NaCl and KCl) at elevated pressures (up to 35,000 psi) and elevated temperatures (up to 450 ºF) on the viscosity of water based mud has been presented.
Oilfield produced water accounts for 98% of all waste generated in oil and gas exploration and processing. This process water may contain up to 1000 ppm total oil and grease, which must be treated prior to discharge. A novel inorganic adsorbent was designed to have high affinity towards such organics. Lab scale evaluations of this adsorbent on production effluents obtained from an onshore site consistently yields TOG removal > 96%. This was found to be a significant improvement over the chemically assisted DAF at 74% in similar lab scale evaluations. This novel technology has the potential to provide a substancial reduction in capital and operating costs for water treatment.
Cinar, Yildiray (The University of New South Wales) | Arns, Christoph (The University of New South Wales) | Dehghan Khalili, Ahmad (The University of New South Wales) | Yanici, Sefer (The University of New South Wales)
Resistivity measurements play a key role in hydrocarbon in place calculations for oil and gas reservoirs. They are a direct indi-cator of fluid saturation and connected pore space available in the formation. Carbonate rocks, which host around half of the world's hydrocarbons, exhibit a wide range of porosities with scales spanning from nanometres to centimetres. The often sig-nificant amount of microporosity displayed by Carbonate rocks emphasizes the necessity of an adequate characterization of their micro-features and their contribution to hydrocarbon in place. In this paper we examine upscaling methods to probe for-mation factor of a fully saturated carbonate sample using an X-ray CT based numerical approach and compare to experimental measurements.
Three-dimensional high-resolution X-ray CT enables the numerical calculation of petrophysical properties of interest at the pore scale with resolutions down to a few microns per voxel. For more complex and heterogeneous samples however, a direct calculation of petrophysical properties is not feasible, since the required resolution and a sufficient field of view cannot be obtained simultaneously. Thus an integration of measurements at different scale is required. In this study a carbonate sample of 38mm in diameter is first scanned using the X-ray CT method with a resolution of 26µm. After accompanying experimental measurements on the full plug, four 5mm plugs were drilled vertically from this sample and X-ray CT images of these plugs acquired at resolutions down to 2.74 µm. We calculate the porosity of the sample (macro- and micro-porosities) using the phase separation methods and then predict the formation factor of the sample at several scales using a Laplace solver. The formation factor is calculated by using a general value of m=2 as cementation factor for intermediate porosity voxels. We compare to experimental measurements of formation factor and porosity both at the small plug and full plug scale and find good agreement.
To assess the degree of uncertainty of the numerical estimate, we probe the extent of heterogeneity by investigating the size of a representative elementary volume (REV) for formation factor. We find that for the considered heterogeneous carbonate sam-ple, formation factor varies considerably over intervals less than a centimetre. Our results show that this variation could be explained by different cementation exponents applied at the micro-voxel scale, with the exemption of one plug, for which the cementation exponent would have to be unreasonably low. These cementation factors are derived by direct comparison be-tween numerical simulation and experiment. We conclude that for one plug an error in experimental measurement might have occurred. The numerical approach presented here therefore aids in quality control. Excluding this plug in the upscaling proce-dure improves the agreement with the experimental result for the whole core while still underestimating formation factor. Al-lowing for a constant m=2 in the simulation at the small scale and using directly the resulting relationship between porosity and formation factor in the upscaling process leads to an overestimation of formation factor.
Historically, shale instability is a challenging issue when drilling reactive formations using water-based muds (WBM). Shale instability leads to shale sloughing, stuck pipe, and shale disintegration causing an increase in fines that affects the rate of penetration. To characterize shale instability, laboratory tests including Linear Swell Meter (LSM), shale-erosion and slake-durability are conducted in industry. These laboratory tests, under different flow conditions, provide shale-fluid interaction parameters which are indicative of shale instability. The composition of WBM is designed to optimize these interaction parameters, so that when used in the field the fluid helps achieve efficient drilling.
This paper demonstrates modeling of shale-fluid interaction parameters obtained from the LSM test. In the standard LSM test, a laterally confined cylindrical shale sample is exposed to WBM at a specific temperature and its axial swelling is measured with time. The swelling reaches a plateau which is characterized by a shale-fluid interaction parameter called % final swelling volume (A). A typical LSM test runs for around 48-72 hours and many tests may be needed to optimize fluid composition.
In this work, a method/model is developed to predict final swelling volume (A) as a function of the Cation exchange capacity (CEC) of the shale and salt concentration in the fluid (prominent factors affecting shale swelling). An empirical model in the form of A = f(CEC)*f(salt) which describes the explicit dependence on the influencing variables is developed and validated for 16 different shale samples at various salt concentrations. This model would significantly reduce LSM laboratory trials saving time and money. It could also enable rig personnel to obtain quick measure of shale characteristics so that WBM composition could be adjusted immediately to avoid shale instability issues.
Stanitzek, Theo (AkzoNobel) | De Wolf, Corine (AkzoNobel) | Gerdes, Steffan (Fangmann Energy Services) | Lummer, Nils R. (Fangmann Energy Services) | Nasr-El-Din, Hisham A. (Texas A&M University) | Alex, Alan K. (AkzoNobel)
Matrix acidizing of high temperature gas wells is a difficult task, especially if these wells are sour or if they are completed with high chrome content tubulars. These harsh conditions require high loadings of corrosion inhibitors and intensifiers in addition to hydrogen sulfide scavengers and iron control agents. Selection of these chemicals to meet the strict environmental regulations adds to the difficulty in dealing with such wells. Recently, a new environmentally friendly chelating agent, glutamic acid -diacetic acid (GLDA), has been developed and extensively tested for carbonate and sandstone formations. Significant permeability improvements have been shown in previous papers over a wide range of conditions. In this paper we evaluate the results of the first field application of this chelating agent to acidize a sour, high temperature, tight gas well completed with high chrome content tubulars.
Extensive laboratory studies were conducted before the treatment, including: corrosion tests, core flood experiments, compatibility tests with reservoir fluids, and reaction rate measurements using a rotating disk apparatus. The treatment started by pumping a preflush of mutual solvent and water wetting surfactant, followed by the main stage consisting of 20 wt% GLDA with a low concentration of a proper corrosion inhibitor. Following the treatment, the well was put on production, and samples of flow back fluids were collected. The concentrations of various ions were determined using ICP. Various analytical techniques were used to determine the concentration of GLDA and other organic compounds in the flow back samples.
The treatment was applied in the field without encountering any operational problems. A significant increase in gas production that exceeded operator expectations was achieved. Unlike previous treatments where HCl or other chelates were used, the concentrations of iron, chrome, nickel, and molybdenum in the flow back samples were negligible, confirming low corrosion of well tubulars. Improved productivity and longer term performance results confirm the effectiveness of the new chelate as a versatile stimulation fluid.
Thread compound "dope?? in the vernacular, has been used routinely in assembling joints of casing and tubing. The practice in almost universal application in the oil and gas industry involves the manual application of the lubricant in a fashion that is rudimentary, non-systematic and unquantifiable. There is evidence presented in this paper that damage to the near-well zone and other unpleasant events may be associated with the thread compound.
This paper presents the results of both laboratory and field investigations quantifying the effects of the dope on near-well damage. During the assembly of tubing and casing a portion of the thread compound is exuded inside and outside the connection and gets access to the well fluids through the tubing and annular space. Studies presented here show that the dope forms a suspension which penetrates and damages the formation. The studies used standard fluid circulation velocities during typical completion operations.
To characterize and quantify the problem, core samples from the El Tordillo field, with different permeabilities were used. The samples were subjected to the circulation of the suspension created by the thread compound and the completion fluid, measuring the change in the core permeability. The work simulated the well conditions during water injection for water injection wells and during acid treatments for producer wells. A significant reduction in permeability, manifested by a fast and a very large increase in pressure, was measured, at the front face of the core sample. The same measurements showed a far smaller impact in the core body suggesting very minor penetration of dope particles.
This paper describes the laboratory and field work, with description of the test protocols, well conditions and laboratory emulation of field conditions that were used.